Citation: LI Hui-Hua, GE You, ZHU Hong-Li, FENG Xiao-Miao, LIU Yu-Ge. Preparation by Electro-Deposition Method and Application in Flexible All-Solid-State Supercapacitors of Poly(3, 4-ethylenedioxythiophene) Microtubes[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1799-1807. doi: 10.11862/CJIC.2018.231 shu

Preparation by Electro-Deposition Method and Application in Flexible All-Solid-State Supercapacitors of Poly(3, 4-ethylenedioxythiophene) Microtubes

LI Hui-Hua ¹ ,
GE You ¹ ,
ZHU Hong-Li ¹ ,
FENG Xiao-Miao ^1,, ,
LIU Yu-Ge ^2,,

1.
Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials(IAM); Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM); Nanjing University of Posts & Telecommunications, Nanjing 210023, China
2.
School of Chemistry and Chemical Engineering, Lingnan Normal University, Zhanjiang, Guangdong 524000, China

Corresponding author: FENG Xiao-Miao, iamxmfeng@njupt.edu.cn LIU Yu-Ge, liuyugehb@126.com
Received Date: 16 April 2018
Revised Date: 14 July 2018

Figures(8)

Poly(3, 4-ethylenedioxythiophene) (PEDOT) microtube electrodes doped with different acids and surfactants were obtained by one-step electrochemical deposition method and could be used for flexible and all-solid-state supercapacitors (SCs). We also investigated the effect of deposition time on the capacitance performance of PEDOT microtubes doped with the same acid medium and surfactant. The structures of the final product were characterized by different characterization techniques including scanning electron microscopy (SEM) and FT-IR spectra. The electrochemical results showed that the capacitance of PEDOT microtubes doped with sulfuric acid (H₂SO₄) and sodium dodecyl sulfate (SDS) could be improved significantly. The areal capacitance of the prepared supercapacitor with deposition time of 600 s could achieve to 113.5 mF·cm^-2 at the scan rate of 10 mV·s^-1. The areal capacitances under the different bending angles remained at 93% of initial capacitive value revealing that the supercapacitor had highly mechanical stability. In addition, it remained 95.5% of the initial capacitive value after 2 000 cycles at a current density of 0.6 mA·cm^-2 showing its superior cycling stability. The prepared flexible all-solid-state supercapacitor can power a light-emitting-diode (LED) which meets the practical applications of micro-power supplies.
- electro-deposition,
- solid-state,
- flexible,
- supercapacitor
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