Citation: BU De-Yan, GUO Yan-Hong, ZHENG Tao, SUN Ai-Jing, WANG Zuo-Xiang. Syntheses, Crystal Structures and Spectral Properties of Cu(Ⅱ), Cd(Ⅱ) Complexes with 2-Methyl-5-(2-pyridyl)-1, 3, 4-oxadiazole[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1875-1882. doi: 10.11862/CJIC.2018.230 shu

Syntheses, Crystal Structures and Spectral Properties of Cu(Ⅱ), Cd(Ⅱ) Complexes with 2-Methyl-5-(2-pyridyl)-1, 3, 4-oxadiazole

College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: WANG Zuo-Xiang, wangzx0908@aliyun.com
Received Date: 30 May 2018
Revised Date: 27 June 2018

Figures(6)

2-Methyl-5-(2-pyridyl)-1, 3, 4-oxadiazole(L), [Cu₂L₂(μ-Cl)₂Cl₂] (1) and[CdL₂(NO₃)₂] (2) were synthesized and characterized by single crystal X-ray diffraction, IR, UV-Vis, fluorescence and TGA. Ligand L and complex 2 crystallize in monoclinic system. Complex 1 crystallizes in triclinic system. The space groups of compound L, complexes 1 and 2 are P2₁/c, P1 and C2/c, respectively. Complex 1 is a binuclear Cu(Ⅱ) complex bridged by two Cl atoms (Cl1, Cl1^ⅰ) and has a distorted tetragonal pyramidal geometry with[CuCl₃N₂]. Complex 2 has a distorted octahedral geometry with[CdN₄O₂].
- crystal structure,
- 1, 3, 4-oxadiazole,
- synthesis,
- Cu(Ⅱ),
- Cd(Ⅱ)complexes
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