Citation: BU De-Yan, GUO Yan-Hong, ZHENG Tao, SUN Ai-Jing, WANG Zuo-Xiang. Syntheses, Crystal Structures and Spectral Properties of Cu(Ⅱ), Cd(Ⅱ) Complexes with 2-Methyl-5-(2-pyridyl)-1, 3, 4-oxadiazole[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1875-1882. doi: 10.11862/CJIC.2018.230 shu

Syntheses, Crystal Structures and Spectral Properties of Cu(Ⅱ), Cd(Ⅱ) Complexes with 2-Methyl-5-(2-pyridyl)-1, 3, 4-oxadiazole

College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: WANG Zuo-Xiang, wangzx0908@aliyun.com
Received Date: 30 May 2018
Revised Date: 27 June 2018

Figures(6)

2-Methyl-5-(2-pyridyl)-1, 3, 4-oxadiazole(L), [Cu₂L₂(μ-Cl)₂Cl₂] (1) and[CdL₂(NO₃)₂] (2) were synthesized and characterized by single crystal X-ray diffraction, IR, UV-Vis, fluorescence and TGA. Ligand L and complex 2 crystallize in monoclinic system. Complex 1 crystallizes in triclinic system. The space groups of compound L, complexes 1 and 2 are P2₁/c, P1 and C2/c, respectively. Complex 1 is a binuclear Cu(Ⅱ) complex bridged by two Cl atoms (Cl1, Cl1^ⅰ) and has a distorted tetragonal pyramidal geometry with[CuCl₃N₂]. Complex 2 has a distorted octahedral geometry with[CdN₄O₂].
- crystal structure,
- 1, 3, 4-oxadiazole,
- synthesis,
- Cu(Ⅱ),
- Cd(Ⅱ)complexes
1. [1]
  Holla B S, Gonsalves R, Shenoy S. Eur. J. Med. Chem., 2000, 35:267-271 doi: 10.1016/S0223-5234(00)00154-9
2. [2]
  Boström J, Hogner A, Llinas A, et al. J. Med. Chem., 2012, 55:1817-1830 doi: 10.1021/jm2013248
3. [3]
  Ishii M, Jorge S D, de Oliveira A A, et al. Bioorg. Med. Chem., 2011, 19:6292-6301 doi: 10.1016/j.bmc.2011.09.009
4. [4]
  Bhandari S V, Parikh J K, Bothara K G, et al. J. Enzyme Inhib. Med. Chem., 2010, 25:520-530 doi: 10.3109/14756360903357585
5. [5]
  LIU Jian-Chao, WANG Wei-Dong, HE Hong-Wu. Chinese J. Org. Chem., 2014, 34(7):1447-1457
6. [6]
  Banerjee A G, Das N, Shengule S A, et al. Eur. J. Med. Chem., 2015, 101:81-95 doi: 10.1016/j.ejmech.2015.06.020
7. [7]
  Ilango K, Valentina P, Kumar G, et al. Med. Chem., 2015, 11:753-763 doi: 10.2174/1573406411666150519112037
8. [8]
  Verma G, Chashoo G, Ali A, et al. Bioorg. Chem., 2018, 77:106-124 doi: 10.1016/j.bioorg.2018.01.007
9. [9]
  Dewangan, D, Verma V S, Nakhate K T, et al. Med. Chem. Res., 2016, 25:2143-2154 doi: 10.1007/s00044-016-1641-8
10. [10]
  Wang B L, ZhuH W, Ma Y, et al. J. Agric. Food. Chem., 2013, 61:5483-5493 doi: 10.1021/jf4012467
11. [11]
  Adachi C, Tokito S, Tsutsui T, et al. Jpn. J. Appl. Phys., 1988, 28:L269-L271
12. [12]
  Bouanis M, Tourabi M, Nyassi A, et al. Appl. Surf. Sci., 2016, 389:952-966 doi: 10.1016/j.apsusc.2016.07.115
13. [13]
  Gurudatt D M, Mohana K N. Ind. Eng. Chem. Res., 2014, 53:2092-2105 doi: 10.1021/ie402042d
14. [14]
  Raj X J, Rajendran N. Prot. Met. Phys. Chem. Surf., 2013, 49:763-775 doi: 10.1134/S2070205113060257
15. [15]
  Mohamed N A. Polym. Degrad. Stab., 2017, 146:42-45 doi: 10.1016/j.polymdegradstab.2017.09.017
16. [16]
  Shavaleev N M, Scopelliti R, Gratzel M, et al. Inorg. Chim. Acta, 2013, 394:295-299 doi: 10.1016/j.ica.2012.07.026
17. [17]
  Bharty M K, Bharti A, Dani R K, et al. J. Mol. Struct., 2012, 1011:34-31 doi: 10.1016/j.molstruc.2011.12.015
18. [18]
  Slyvka Y, Goreshnik E, Veryasov G, et al. Polyhedron, 2017, 133:319-326 doi: 10.1016/j.poly.2017.05.052
19. [19]
  Bharty M K, Dani R K, Nath P, et al. Polyhedron, 2015, 98:84-95 doi: 10.1016/j.poly.2015.05.045
20. [20]
  Garcia A, Machado R C, Grazul R M, et al. J. Biol. Inorg. Chem., 2016, 21:275-292 doi: 10.1007/s00775-016-1338-y
21. [21]
  Chaves J D S, Tunes L G, Franco C H D J, et al. Eur. J. Med. Chem., 2017, 127:727-739 doi: 10.1016/j.ejmech.2016.10.052
22. [22]
  Gallego B, Kaluderovic M R, Kommera H, et al. Invest. New Drugs, 2011, 29:932-944 doi: 10.1007/s10637-010-9449-8
23. [23]
  Köhler C, Rentschler E. Eur. J. Inorg. Chem., 2016, 13-14:1955-1960
24. [24]
  James C A, Poirier B, Grise C, et al. Tetrahedron Lett., 2006, 47:511-514 doi: 10.1016/j.tetlet.2005.11.057
25. [25]
  Sheldrick G M. Acta Crystallogr. Sect. A, 2008, A64:112-122
26. [26]
  Li Y, Zhang C G, Cai L Y. J. Coord. Chem., 2013, 66:3100-3112 doi: 10.1080/00958972.2013.826350
27. [27]
  SHENG Jun-Feng, WANG Ning, CAI Liang-Ying, et al. Chinese J. Inorg. Chem., 2015, 31(2):405-412
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