Citation: CHENG Zhi-Lin, CAO Bao-Chong, LIU Zan. Halloysite Nanotubes-Templated One-Step Preparation for Carbon Nanotubes/Carbon Nanorods Mixed Carbon Nanomaterials[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1808-1816. doi: 10.11862/CJIC.2018.228 shu

Halloysite Nanotubes-Templated One-Step Preparation for Carbon Nanotubes/Carbon Nanorods Mixed Carbon Nanomaterials

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China

Corresponding author: CHENG Zhi-Lin, zlcheng224@126.com
Received Date: 24 April 2018
Revised Date: 31 July 2018

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This work developed a novel approach to prepare the CNTs/CNRs mixed nanomaterials by nanocasting method with tuning HNTs/PVA proportion, which employed HNTs as template and PVA as carbon source. We explored the effect of HNTs/PVA proportion on the structure of the mixed carbon nanomaterials. A series of characterizations, such as XRD, FTIR, Raman, N₂ adsorption-desorption, TEM, SEM, resistivity and dispersibility, were used to determine the structure of the CNTs/CNRs mixed nanomaterials. The results found that PVA nanocasting content in the hollow nanostructure of HNTs affected the increase of CNRs in the CNTs/CNRs mixed nanomaterials. Upon the mass proportion of PVA/HNTs up to 1:1, the pore volume of the CNTs/CNRs mixed nanomaterials approached to the maximum of 2.142 cm³·g^-1 and the specific surface area was up to 583 m²·g^-1, and definitely showed a better conductivity and dispersibility, demonstrating that a lower PVA nanocasting content in HNTs could fulfilled a higher CNTs content in the CNTs/CNRs mixed nanomaterials.
- porous carbon,
- nanotechnology,
- HNTs,
- hard template
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沈阳化工大学材料科学与工程学院沈阳 110142