Citation: NIU Ru-Yue, LIU Peng-Cheng, LI Wei, WANG Shuang, LI Jin-Ping. Catalytic Combustion of Ventilation Air Methane over Co₃O₄ Rectangular Prism[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1929-1935. doi: 10.11862/CJIC.2018.223 shu

Catalytic Combustion of Ventilation Air Methane over Co₃O₄ Rectangular Prism

NIU Ru-Yue ¹ ,
LIU Peng-Cheng ¹ ,
LI Wei ¹ ,
WANG Shuang ^1,2,, ,
LI Jin-Ping ^1,,

1.
Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, Taiyuan 030024, China
2.
College of Environmental Science and Engineering, Taiyuan University of Technology, Jinzhong, Shanxi 030600, China

Corresponding author: WANG Shuang, wangshuang@tyut.edu.cn LI Jin-Ping, jpli211@hotmail.com
Received Date: 30 May 2018
Revised Date: 12 July 2018

Figures(7)

The Co₃O₄ rectangular prism assembled by nanoparticles has been successfully fabricated via a two-step method. The first step involves the synthesis of CoC₂O₄·2H₂O rectangular prism by a simple condensing reflux method. The second step includes the calcination of the as-prepared CoC₂O₄·2H₂O rectangular prism at 350℃ for 2 h, causing its decomposition to form Co₃O₄ rectangular prism without destructing of the original morphology. The mechanical properties were characterized by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), nitrogen adsorption-desorption, scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and H₂ temperature-programmed reduction (H₂-TPR). The results showed that the catalytic activity of Co₃O₄ rectangular prism for the combustion of ventilation air methane was higher than that of commercial Co₃O₄. The superior catalytic performance could be attributed to the high surface Co³⁺ content, high surface adsorbed oxygen content, and exposing the {111} planes.
- industrial catalysis,
- metal oxide catalyst,
- catalytic activity,
- ventilation air methane
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沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic Combustion of Ventilation Air Methane over Co3O4 Rectangular Prism

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Catalytic Combustion of Ventilation Air Methane over Co₃O₄ Rectangular Prism