Citation: LI Hua-Mei, CHEN Yu-Jie, ZHAO Xiao-Hui, DENG Zhao. Fabrication and Electrochemical Performance of Mesoporous α-Fe₂O₃ Anodes for Lithium and Sodium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1670-1676. doi: 10.11862/CJIC.2018.221 shu

Fabrication and Electrochemical Performance of Mesoporous α-Fe₂O₃ Anodes for Lithium and Sodium Ion Batteries

LI Hua-Mei ^1,2 ,
CHEN Yu-Jie ^1,2 ,
ZHAO Xiao-Hui ^1,2,, ,
DENG Zhao ^1,2,,

1.
College of Energy, Soochow Institute for Energy and Materials InnovationS, Soochow University, Suzhou, Jiangsu 215006, China
2.
Jiangsu Provincial Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies, Soochow University, Suzhou, Jiangsu 215006, China

Corresponding author: ZHAO Xiao-Hui, zhaoxh@suda.edu.cn DENG Zhao, zdeng@suda.edu.cn
Received Date: 19 May 2018
Revised Date: 4 July 2018

Figures(7)

A highly ordered mesoporous α-Fe₂O₃ nanoparticle has been synthesized by using SBA-15 as hard template and iron nitrate as iron precursor. α-Fe₂O₃ was employed as an anode material for both lithium and sodium ion batteries. The ordered mesoporous structure of α-Fe₂O₃ alleviated the volume change during the discharge/charge process and improved the wettability of the electrolyte. α-Fe₂O₃ anode delivered high initial discharge capacity of 983.9 and 687.7 mAh·g^-1 with good cycle performance for 100 and 50 cycles in lithium and sodium ion batteries, respectively.
- mesoporous materials,
- template synthesis,
- anode,
- lithium-ion battery,
- sodium-ion battery
1. [1]
  Nižetić S, Barbir F, Papadopoulos A, et al. Int. J. Hydrogen Energy, 2018, 43(11):5794 doi: 10.1016/j.ijhydene.2018.01.208
2. [2]
  Bilgen S, Sarkaya, et al. Energy Sources Part B, 2018, 13(8):1-7
3. [3]
  LI Wei-Wei, PAN Quan-Xiang, YAO Lu, et al. Chinese Journal of Power Sources, 2013, 37(7):1247-1249 doi: 10.3969/j.issn.1002-087X.2013.07.051
4. [4]
  ZHANG Ning, LIU Yong-Chang, CHEN Cheng -Cheng, et al. Chinese J. Inorg. Chem., 2015, 31(9):1739-1750
5. [5]
  Wang B, Chen J S, Wu H B, et al. J. Am. Chem. Soc., 2011, 133(43):17146-17148 doi: 10.1021/ja208346s
6. [6]
  Xu Y H, Jian G Q, Liu Y H, et al. Nano Energy, 2014, 3(1):26-35
7. [7]
  Zhang J J, Sun Y F, Yu Y, et al. J. Power Sources, 2013, 222(2):59-65
8. [8]
  Wang J C, Zhou H, Zhuang J D, et al. Phys. Chem. Chem. Phys., 2015, 17(5):3802-3812 doi: 10.1039/C4CP04228J
9. [9]
  Zhang W D, Wang X Y, Zhou H H, et al. J. Alloys Compd., 2012, 521(6):39-44
10. [10]
  YE Meng-Chao, YANG Wei, SU Chang-Wei, et al. Electroplating & Finishing, 2015, 34(8):415-421 doi: 10.3969/j.issn.1004-227X.2015.08.001
11. [11]
  Wang Z, Luan D, Madhavi S, et al. Chem. Commun., 2011, 47(28):8061-8063 doi: 10.1039/c1cc12111a
12. [12]
  Zhang J J, Huang T, Liu Z L, et al. Electrochem. Commun., 2013, 29:17-20 doi: 10.1016/j.elecom.2013.01.002
13. [13]
  Rao B N, Ramesh Kumar P, Padmaraj O, et al. RSC Adv., 2015, 5(44):34761-34768 doi: 10.1039/C5RA03238E
14. [14]
  Wu Z G, Zhong Y J, Liu J, et al. J. Mater. Chem. A, 2015, 3(18):10092-10099 doi: 10.1039/C5TA01334H
15. [15]
  Zhao D Y, Sun J Y, Li Q Z, et al. Chem. Mater., 2000, 12(2):275-279 doi: 10.1021/cm9911363
16. [16]
  Jiao K, Zhang B, Yue B, et al. Chem. Commun., 2005(45):5618-5620 doi: 10.1039/b512080b
17. [17]
  WU Zhen-Sheng, ZHANG Wei-Min, SUN Zhong-Xi. Acta Chim. Sinica, 2010, 68(8):769-774
18. [18]
  Sing K S W, Everett D H, Haul R A W, et al. Pure Appl. Chem., 1985, 57(4):603-619 doi: 10.1351/pac198557040603
19. [19]
  SONG Fa-Hui, WANG Yi-Long, GUAN Jian-Guo, et al. J. Wuhan University Technl., 2010, 32(5):1-5 doi: 10.3963/j.issn.1671-4431.2010.05.001
20. [20]
  Kumar K N P, Kumar J K, Keizer K, et al. J. Am. Ceram. Soc., 1994, 77(5):1396-1400 doi: 10.1111/jace.1994.77.issue-5
21. [21]
  Li C, Wu X Z, Lou X M, et al. Electrochim. Acta, 2010, 55(9):3089-3092 doi: 10.1016/j.electacta.2010.01.016
22. [22]
  Wu D, Ye J, Chen L, et al. RSC Adv., 2016, 6(62):57009-57012 doi: 10.1039/C6RA10206A
23. [23]
  Fang Y J, Chen Z, Xiao L F, et al. Small, 2018, 14(9):703116
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沈阳化工大学材料科学与工程学院沈阳 110142

Fabrication and Electrochemical Performance of Mesoporous α-Fe2O3 Anodes for Lithium and Sodium Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Fabrication and Electrochemical Performance of Mesoporous α-Fe₂O₃ Anodes for Lithium and Sodium Ion Batteries