Citation: ZHAO Hong-Kun, DING Bo, WANG Xiu-Guang, JIA Fang, YANG En-Cui, ZHAO Xiao-Jun. Crystal Structures and Fluorescence Properties of Cu(Ⅱ)/Ni(Ⅱ) Complexes with 4-(1, 2, 4-Triazol-1-yl)phenol Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1739-1746. doi: 10.11862/CJIC.2018.219 shu

Crystal Structures and Fluorescence Properties of Cu(Ⅱ)/Ni(Ⅱ) Complexes with 4-(1, 2, 4-Triazol-1-yl)phenol Ligand

College of Chemistry, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, China

Corresponding author: YANG En-Cui, encui_yang@163.com ZHAO Xiao-Jun, xiaojun_zhao15@163.com
Received Date: 1 May 2018
Revised Date: 22 June 2018

Figures(4)

Two 4-(1, 2, 4-triazol-1-yl)phenol (hptrz)-based transition metal complexes, {[Ni(H₂O)₂(hptrz)₂(tp)]·2DMF}_n (1) and[Cu(hptrz)₂(SCN)₂]·2H₂O (2) (H₂tp=terephthalic acid), have been prepared and characterized by single-crystal and powder X-ray diffractions, elemental analysis, FT-IR spectra, thermogravimertric and luminescence spectra. X-ray diffraction analysis revealed that 1 is a one-dimensional linear chain with octahedral Ni(Ⅱ) ions extended by bis-unidentate tp^2- anions; whereas 2 exhibits a centrosymmetric mononuclear entity. The neutral hptrz ligand in the both complexes serves as terminal ligands to complete the metal coordination sphere and to help to assemble the low-dimensional aggregates into a high-dimensional supramolecular architecture by O-H…O hydrogen-bonding interactions. Additionally, the complexes display strong emissions in UV region originated from intraligand electronic transfer.
- 4-(1, 2, 4-triazol-1-yl)phenol,
- Cu(Ⅱ)/Ni(Ⅱ) complexes,
- crystal structure,
- luminescent property
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