Citation: GAO Xiang, XU Wei, WU Chang-Li, ZHU Xi-Miao, OU Yong-Cong, WU Jian-Zhong. Syntheses, Crystal Structures and Luminescent Properties of Dinuclear d¹⁰ Complexes Based on a Ligand Formed in Situ by 8-Hydroxyquinoline[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1768-1774. doi: 10.11862/CJIC.2018.213 shu

Syntheses, Crystal Structures and Luminescent Properties of Dinuclear d¹⁰ Complexes Based on a Ligand Formed in Situ by 8-Hydroxyquinoline

Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China

Corresponding author: ZHU Xi-Miao, zhuximiao@m.scnu.edu.cn OU Yong-Cong, ouyongcong@m.scnu.edu.cn WU Jian-Zhong, wujzh@scnu.edu.cn
Received Date: 25 May 2018
Revised Date: 17 June 2018

Figures(4)

Three novel d¹⁰ complexes[M₂(HL)₃] NO₃·H₂O (M=Cd (1), Zn (2, 3), H₂L=7, 7'-(ethane-1, 1-diyl)diquinolin-8-ol) have been synthesized under solvothermal conditions. Single crystal X-ray diffraction analysis reveals that the complexes have the same coordination positive charged unit, [M₂(HL)₃]⁺, but different lattice structures due to the different places of the guest molecules. Complexes 1 and 3 crystallize in hexagonal system (P6₃/m) and complex 2 crystallizes in trigonal system (R3). The metal ions are six-coordinated with three oxygen atoms and three nitrogen atoms of three HL^- ligands, presenting a slightly distorted octahedron geometry. There are abundant weak interactions between HL^- ligands and guest molecule (NO₃^- and H₂O), which play a vital role in the form of the crystal packing. These complexes show good thermal stabilities and exhibit green fluorescence. Further, the fluorescence of ligand H₂L extracted from the complex 1 has also been studied firstly and blue light emission of it was observed.
- d¹⁰ complexes,
- in situ reaction,
- crystal structures,
- weak interaction,
- luminescent properties
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Syntheses, Crystal Structures and Luminescent Properties of Dinuclear d¹⁰ Complexes Based on a Ligand Formed in Situ by 8-Hydroxyquinoline