Citation: MU Jin-Cheng, JIANG Sai, JI Sheng-Fu. Preparation and Properties for Aza-Micheal Addition Reaction of Magnetic Y-MOF@SiO₂@Fe₃O₄ Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1753-1760. doi: 10.11862/CJIC.2018.209 shu

Preparation and Properties for Aza-Micheal Addition Reaction of Magnetic Y-MOF@SiO₂@Fe₃O₄ Catalysts

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
2.
Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of XPCC, Tarim University, Alar, Xinjiang 843300, China

Corresponding author: JI Sheng-Fu, jisf@mail.buct.edu.cn
Received Date: 11 May 2018
Revised Date: 27 June 2018

Figures(7)

The magnetic Y-MOF@SiO₂@Fe₃O₄ catalysts with different Y-MOF contents were synthesized by encapsulating magnetic SiO₂@Fe₃O₄ nanospheres into Y-MOF through an in-situ method. The structure of the catalyst was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), infrared spectroscopy (FT-IR), vibration sample magnetometer (VSM) and the N₂ adsorption-desorption test. The performance of the catalyst for Aza-Micheal addition reaction with aniline and methyl acrylate was evaluated. The results showed that Y-MOF was uniformly coated on the surface of the SiO₂@Fe₃O₄ nanospheres to form a core-shell magnetic Y-MOF@SiO₂@Fe₃O₄ catalyst. The catalysts exhibited good superparamagnetism. When Y-MOF content was 43.3% (w/w), the Y-MOF@SiO₂@Fe₃O₄ catalyst had better catalytic performance for the Aza-Micheal addition reaction. The conversion of methyl acrylate was 88.3% and the selectivity of N-(β-methoxycarbonylethyl) aniline was 99.8%. After reaction, the catalyst was recovered by magnetic recovery. It was reused five times, and still has high conversion and selectivity.
- magnetic,
- Y-MOF@SiO₂@Fe₃O₄,
- catalyst,
- Aza-Micheal reaction
1. [1]
  Ying A, Li Z F, Yang J G, et al. J. Org. Chem., 2014, 79(14):6510-6516 doi: 10.1021/jo500937a
2. [2]
  Robiette R, Tran T V, Cordi A, et al. Synthesis, 2010, 2010(18):3138-3142 doi: 10.1055/s-0030-1258176
3. [3]
  Bassam N, Laure C, Jean-Franois B, et al. Green Chem., 2013, 15(7):1900-1909 doi: 10.1039/c3gc37054b
4. [4]
  Szánti-Pintér E, Maksó L, GömöryÁ, et al. Steroids, 2017, 123:61-66 doi: 10.1016/j.steroids.2017.05.006
5. [5]
  Zhang J L, Zhang Y L, Liu X H, et al. Adv. Synth. Catal., 2014, 356(17):3545-3551 doi: 10.1002/adsc.v356.17
6. [6]
  Ardizzoia G A, Brenna S, Therrien B. Dalton Trans., 2012, 41(3):783-790 doi: 10.1039/C1DT11191D
7. [7]
  Didier D, Meddour A, Bezzenine-Lafollée S, et al. Eur. J. Org. Chem., 2011(14):2678-2684
8. [8]
  Siddiqui I R, Shamim S, Kumar D, et al. New J. Chem., 2012, 36:2209-2214 doi: 10.1039/c2nj40469a
9. [9]
  Kang Q, Zhang Y G. Org. Biomol. Chem., 2011, 9(19):6715-6720 doi: 10.1039/c1ob05429e
10. [10]
  Mokhtar M, Saleh T S, Basahel S N. J. Mol. Catal. A:Chem., 2012, 353:122-131
11. [11]
  Jie L, Liang Z B, Zou R Q, et al. Adv. Mater., 2017, 29(30):17011-17032
12. [12]
  Mitchell L, Williamson P, Ehrlichová B, et al. Chem. Eur. J., 2014, 20:17185-17197 doi: 10.1002/chem.201404377
13. [13]
  Nguyen L T L, Nguyen T T, Nguyen K D, et al. Appl. Catal., A, 2012, 425-426:44-52 doi: 10.1016/j.apcata.2012.02.045
14. [14]
  WANG Yue, GONG Yong, XU Hai-Juan, et al. Chinese J. Inorg. Chem., 2018, 34(5):906-916
15. [15]
  Ricco R, Malfatti L, Takahashi M, et al. J. Mater. Chem. A, 2013, 1(42):13033-13045 doi: 10.1039/c3ta13140h
16. [16]
  Zhu Q L, Xu Q. Chem. Soc. Rev., 2014, 43(16):5468-5512 doi: 10.1039/C3CS60472A
17. [17]
  Huang L, Cai J, He M, et al. Ind. Eng. Chem. Res., 2018, 57(18):6201-6209 doi: 10.1021/acs.iecr.7b05294
18. [18]
  Li Q Y, Jiang S, Ji S F, et al. Ind. Eng. Chem. Res., 2014, 53(39):14948-14955 doi: 10.1021/ie502489q
19. [19]
  LI Qing-Yuan(李庆远), MUHAMMAD Ammar, JI Sheng-Fu (季生福), et al. Acta Petrolei Sinica(石油学报(石油加工)), 2014,30(1):126-133
20. [20]
  Li Q Y, Jiang S, Ji S F, et al. J. Porous Mater., 2015, 22(5):1205-1214 doi: 10.1007/s10934-015-9997-6
21. [21]
  Jiang S, Yan J L, Habimana F, et al. Catal. Today, 2016, 264:83-90 doi: 10.1016/j.cattod.2015.10.003
22. [22]
  Shen L L, Yang L, Fan Y, et al. CrystEngComm, 2015, 17(48):9363-9369 doi: 10.1039/C5CE01718A
23. [23]
  Wang S Y, Shan L, Fan Y, et al. J. Solid State Chem., 2017, 245:132-137 doi: 10.1016/j.jssc.2016.10.006
24. [24]
  Datcu A, Roques N, Jubera V, et al. Chem. Eur. J., 2011, 17(13):3644-3656 doi: 10.1002/chem.v17.13
25. [25]
  Chen Y, Ma S. Rev. Inorg. Chem., 2012, 32:81-100
26. [26]
  Pagis C, Ferbinteanu M, Rothenberg G. ACS Catal., 2016, 6:6063-6072 doi: 10.1021/acscatal.6b01935
27. [27]
  Luo J H, Xu H W, Liu Y, et al. J. Am. Chem. Soc., 2008, 130:9626-9627 doi: 10.1021/ja801411f
28. [28]
  YANG Qing-Xiang, REN Shuang-Shuang, ZHAO Qian-Qian, et al. Chinese J. Inorg. Chem., 2017, 33(5):843-852
29. [29]
  Liu X, Wang J Y, Li Q Y, et al. J. Rare. Earths., 2014, 32(2):189-194 doi: 10.1016/S1002-0721(14)60050-8
30. [30]
  Liu H F, Zeng P H, Ji S F, et al. Catal. Today, 2011, 175(1):293-298 doi: 10.1016/j.cattod.2011.04.042
31. [31]
  Ji J H, Zeng P H, Ji S F, et al. Catal. Today, 2010, 158(3):305-309
32. [32]
  Zou X Q, Goupil J M, Thomas S, et al. J. Phys. Chem. C, 2012, 116(31):16593-16600 doi: 10.1021/jp3044016
33. [33]
  Shu Y, Meng Y, Chen M L, et al. Chin. Chem. Lett., 2015, 26(12):1460-1464 doi: 10.1016/j.cclet.2015.10.013
34. [34]
  Mahalakshmi G, Balachandran V. Spectrochim. Acta, Part A, 2014, 124(8):535-547
35. [35]
  Wang F, Deng K J, Wu G L, et al. J. Inorg. Organomet. Polym., 2012, 22(4):680-685 doi: 10.1007/s10904-011-9498-2
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Properties for Aza-Micheal Addition Reaction of Magnetic Y-MOF@SiO2@Fe3O4 Catalysts

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通讯作者: 陈斌, bchen63@163.com

Preparation and Properties for Aza-Micheal Addition Reaction of Magnetic Y-MOF@SiO₂@Fe₃O₄ Catalysts