Citation: CHEN Wei, YAN Sen-Bo, YAN Hong, LU Chang-Sheng. Transform ACQ Luminophores to AIEgens via Engineering the Variable C-C Bonds of o-Carboranes in Fluorescent Cores[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1413-1420. doi: 10.11862/CJIC.2018.187 shu

Transform ACQ Luminophores to AIEgens via Engineering the Variable C-C Bonds of o-Carboranes in Fluorescent Cores

CHEN Wei ¹ ,
YAN Sen-Bo ² ,
YAN Hong ^1,, ,
LU Chang-Sheng ^1,3,,

1.
School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2.
College of Mechanics and Materials, Hohai University, Nanjing 210000, China
3.
National Demonstration Center for Experimental Chemistry Education of Nanjing University, Nanjing 210023, China

Corresponding author: YAN Hong, hyan1965@nju.edu.cn LU Chang-Sheng, luchsh@nju.edu.cn
Received Date: 23 April 2018
Revised Date: 20 May 2018

Figures(5)

The variable C-C bond of o-carborane cage was treated as a vibrational factor. A temptation to synthesize AIE-active o-carborane luminophores were carried out via coupling o-carborane with conventional luminophores who suffered from ACQ (aggregation-caused quenching) effect. Meanwhile, the photophysical properties were investigated by UV-Vis spectra, DFT calculations, PL spectra and crystal structure analysis. The results indicate that different substituents (H, ethyl and phenyl) in o-carboranes could remarkably affect its vibration performance. Ultimately, photophysical properties can be tuned from ACQ to AIE.
- carborane,
- aggregation-caused quenching,
- aggregation-induced emission
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