Citation: LIU Guang, YAO Rui, ZHAO Yong, WANG Mu-Heng, LI Na, Li Jin-Ping. Ni/NiFe₂O₄ Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1494-1500. doi: 10.11862/CJIC.2018.186 shu

Ni/NiFe₂O₄ Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst

Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: Li Jin-Ping, jpli211@hotmail.com
Received Date: 13 April 2018
Revised Date: 8 May 2018

Figures(6)

Ni/NiFe₂O₄ nanorods encapsulated in onion-like N-doped carbon (ONC) nanolayers was prepared by the pyrolysis of NiFe-based coordination polymer precursor under N₂ atmosphere. Compared with Ni@ONC, NiFe₂O₄, and commercial RuO₂ electrocatalysts, benefiting by the promoted electronic conductivity and enlarged electrochemical surface area (0.149 mF) from synergistic effects between the ONC nanolayers and encapsulated Ni/NiFe₂O₄ heterostructure, the as-prepared Ni/NiFe₂O₄@ONC hybrid nanorod exhibits extraordinary electrocatalytic activity towards oxygen evolution reaction (OER) with an overpotential of~299 mV at 10 mA·cm^-2 and a Tafel slope of 73 mV·dec^-1.
- water splitting,
- oxygen evolution catalysts,
- N-doped onion-like carbon,
- nickel-iron oxides,
- mesoporous heterostructure
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通讯作者: 陈斌, bchen63@163.com

Ni/NiFe₂O₄ Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst