Citation: LIU Guang, YAO Rui, ZHAO Yong, WANG Mu-Heng, LI Na, Li Jin-Ping. Ni/NiFe₂O₄ Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1494-1500. doi: 10.11862/CJIC.2018.186 shu

Ni/NiFe₂O₄ Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst

Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: Li Jin-Ping, jpli211@hotmail.com
Received Date: 13 April 2018
Revised Date: 8 May 2018

Figures(6)

Ni/NiFe₂O₄ nanorods encapsulated in onion-like N-doped carbon (ONC) nanolayers was prepared by the pyrolysis of NiFe-based coordination polymer precursor under N₂ atmosphere. Compared with Ni@ONC, NiFe₂O₄, and commercial RuO₂ electrocatalysts, benefiting by the promoted electronic conductivity and enlarged electrochemical surface area (0.149 mF) from synergistic effects between the ONC nanolayers and encapsulated Ni/NiFe₂O₄ heterostructure, the as-prepared Ni/NiFe₂O₄@ONC hybrid nanorod exhibits extraordinary electrocatalytic activity towards oxygen evolution reaction (OER) with an overpotential of~299 mV at 10 mA·cm^-2 and a Tafel slope of 73 mV·dec^-1.
- water splitting,
- oxygen evolution catalysts,
- N-doped onion-like carbon,
- nickel-iron oxides,
- mesoporous heterostructure
1. [1]
  XIE Ying-Peng, WANG Guo-Sheng, ZHANG En-Lei, et al. Chinese J. Inorg. Chem., 2017, 33(2):177-209 doi: 10.11862/CJIC.2017.030
2. [2]
  ZHANG Chao-Ying, WANG Ping, LIU Yan-Yan, et al. Chinese J. Inorg. Chem., 2017, 33(7):1132-1138 doi: 10.11862/CJIC.2017.170
3. [3]
  Seh Z W, Kibsgaard J, Dickens C F, et al. Science, 2017, 355(6321):eaad4998 doi: 10.1126/science.aad4998
4. [4]
  Hunter B M, Gray H B, Müller A M. Chem. Rev., 2016, 116(22):14120-14136 doi: 10.1021/acs.chemrev.6b00398
5. [5]
  HE Yang-Hua, XU Jin-Ming, WANG Fa-Nan, et al. Chem. Ind. Eng. Prog., 2016, 35(7):2057-2062
6. [6]
  Liu G, Gao X S, Wang K F, et al. Int. J. Hydrogen Energy, 2016, 41(40):17976-17986 doi: 10.1016/j.ijhydene.2016.07.268
7. [7]
  Xiao C L, Lu X Y, Zhao C. Chem. Commun., 2014, 50(70):10122-10125 doi: 10.1039/C4CC04922E
8. [8]
  Wang Z C, Liu H L, Ge R X, et al. ACS Catal., 2018, 8(3):2236-2241 doi: 10.1021/acscatal.7b03594
9. [9]
  Liu G, Wang K F, Gao X S, et al. Electrochim. Acta, 2016, 211:871-878 doi: 10.1016/j.electacta.2016.06.113
10. [10]
  Yan K L, Shang X, Liu Z Z, et al. Int. J. Hydrogen Energy, 2017, 42(38):24150-24158 doi: 10.1016/j.ijhydene.2017.07.165
11. [11]
  Han L, Dong S J, Wang E K. Adv. Mater., 2016, 28(42):9266-9291 doi: 10.1002/adma.201602270
12. [12]
  Zhou W J, Wu X J, Cao X H, et al. Energy Environ. Sci., 2013, 6(10):2921-2924 doi: 10.1039/c3ee41572d
13. [13]
  GAO Xu-Sheng, LIU Guang, SHI Qin-Fang, et al. Chinese J. Inorg. Chem., 2017, 33(4):623-629 doi: 10.11862/CJIC.2017.080
14. [14]
  Li B Q, Xia Z J, Zhang B S, et al. Nat. Commun., 2017, 8:934 doi: 10.1038/s41467-017-01053-x
15. [15]
  Liu G, Gao X S, Wang K F, et al. Nano Res., 2017, 10(6):2096-2105 doi: 10.1007/s12274-016-1398-x
16. [16]
  CAI Xiao-Qing, JI Zhen-Yuan, SHEN Xiao-Ping, et al. Chinese J. Inorg. Chem., 2017, 33(1):26-32 doi: 10.11862/CJIC.2017.017
17. [17]
  Zhao Y, Nakamura R, Kamiya K, et al. Nat. Commun., 2013, 4:2390 doi: 10.1038/ncomms3390
18. [18]
  Li Y B, Zhao C. ACS Catal., 2017, 7(4):2535-2541 doi: 10.1021/acscatal.6b03497
19. [19]
  Liu G, He D Y, Yao R, et al. Nano Res., 2018, 11(3):1664-1675 doi: 10.1007/s12274-017-1783-0
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通讯作者: 陈斌, bchen63@163.com

Ni/NiFe₂O₄ Nanorods Encapsulated in Onion-like N-Doped Carbon Nanolayers as Efficient Oxygen Evolution Electrocatalyst