Citation: XU Yan, YAO Ai-Hua, JIANG Wen-Qi, WANG De-Ping. Fabrication of Titanium Nitride Nanotube Array as SERS Substrates[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1392-1398. doi: 10.11862/CJIC.2018.185 shu

Fabrication of Titanium Nitride Nanotube Array as SERS Substrates

XU Yan ^1,2 ,
YAO Ai-Hua ^1,2,, ,
JIANG Wen-Qi ² ,
WANG De-Ping ^1,2

1.
School of Materials Science and Engineering, Tongji University, Shanghai 200092, China
2.
Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, Tongji University, Shanghai 200092, China

Corresponding author: YAO Ai-Hua, aihyao@126.com
Received Date: 21 March 2018
Revised Date: 17 May 2018

Figures(7)

TiN nanotube arrays (NTAs) was prepared by calcining the anodized TiO₂ NTAs in NH₃ atmosphere at elevated temperatures, which were used as surface-enhanced Raman scattering (SERS) substrates. The composition, morphology and optical property of the TiN NTAs were characterized by XRD, SEM, UV-Vis and XPS. SERS activity of the TiN NTAs substrates was evaluated using rhodamine 6G (R6G) as probe molecules. The results showed that TiN NTAs were obtained at nitridation temperatures above 800℃, and the nanotubes exhibit ordered tubular structure with pore diameters of 100~200 nm. The UV-Vis spectra exhibited plasmon resonance peaks of TiN NTAs in the wavelength range of 500~600 nm. The TiN NTAs substrates provided superior SERS sensitivity towards R6G, with a detection limit of ~10^-7 mol·L^-1 and the enhancement factor of ~10⁵.
- TiN,
- TiO₂ nanotube arrays,
- surface-enhanced Raman scattering
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沈阳化工大学材料科学与工程学院沈阳 110142