Citation: LIU Yang, WANG Zhen-Ping, WANG Qing-Lun, TONG Yu-Zhang, YANG Chun. Syntheses, Crystal Structures and Magnetic Properties of Two One-Dimensional Heterotrimetallic Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1448-1454. doi: 10.11862/CJIC.2018.179 shu

Syntheses, Crystal Structures and Magnetic Properties of Two One-Dimensional Heterotrimetallic Coordination Polymers

1.
School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China
2.
Department of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: WANG Qing-Lun, wangql@nankai.edu.cn YANG Chun, ychun@hebut.edu.cn
Received Date: 9 February 2018
Revised Date: 11 May 2018

Figures(6)

Two novel heterotrimetallic 1D zigzag chain coordination polymers, {[Cu(Me₂valpn)Dy(DMF)₂(H₂O)Fe(CN)₆]·1.5H₂O·0.5CH₃OH}_n (1) and {[Cu(Me₂valpn) Tb(DMF)₂(H₂O)Fe(CN)₆]·H₂O·CH₃OH}_n (2) (H₂Me₂valpn=N, N'-bis(3-methoxysalicylidene)-2, 2-dimethyl-1, 3-diaminopropane), were prepared by stepwise synthetic approach. Single -crystal X-ray diffraction analysis revealed that each[Fe(CN)₆]^3- is connected with two[Cu(Me₂valpn)]Ln(DMF)₂(H₂O)]³⁺ fragments in a cis-mode. Accordingly, there are two types of bent bridging linkages (Fe-C≡N-Cu and Fe-C≡N-Ln) in the chain besides the diphenoxo bridges between Cu(Ⅱ) and Ln(Ⅲ). In the temperature range of 9.5~300 K, the dc magnetic susceptibilities of complex 1 are consistent with the Curie-Weiss law and give positive Curie-Weiss constants (θ=13.17 K), indicating the presence of predominant ferromagnetic interactions. The AC magnetic measurements reveal that complex 1 shows no slow magnetization relaxation.
- compartmental Schiff base,
- heterotrimetallic complex,
- coordination polymer,
- crystal structure,
- magnetic property
1. [1]
  Meng Y S, Jiang S D, Wang B W, et al. Acc. Chem. Res., 2016, 49(11):2381-2389 doi: 10.1021/acs.accounts.6b00222
2. [2]
  Ganivet C R, Ballesteros B, Torre G, et al. Chem. Eur. J., 2013, 19(4):1457-1465 doi: 10.1002/chem.201202600
3. [3]
  WANG Hong-Sheng, LI Gong-Chun, WU Yan-Chao, et al. Chinese J. Inorg. Chem., 2018, 34(4):655-661
4. [4]
  LI Geng, YAN Wen-Bo, HE Cheng, et al. Chinese J. Inorg. Chem., 2008, 24(11):1767-1771
5. [5]
  CHU Zhao-Hua, CHEN Yan-Min, XIE Qing-Fan. Chinese J. Inorg. Chem., 2013, 29(7):1385-1390
6. [6]
  Osa S, Kido T, Matsumoto N, et al. J. Am. Chem. Soc., 2004, 126(2):420-421 doi: 10.1021/ja037365e
7. [7]
  Liu J L, Wu J Y, Chen Y C, et al. Angew. Chem., Int. Ed., 2014, 53(47):12966-12970 doi: 10.1002/anie.201407799
8. [8]
  Gheorghe R, Cucos P, Andruh M, et al. Chem. Eur. J., 2006, 12(1):187-203 doi: 10.1002/(ISSN)1521-3765
9. [9]
  Liu M J, Hu K Q, Liu C M, et al. Dalton Trans., 2017, 46(20):6544-6552 doi: 10.1039/C7DT00948H
10. [10]
  Gheorghe R, Madalan A M, Costes J P, et al. Dalton Trans., 2010, 39(20):4734-4736 doi: 10.1039/b925636a
11. [11]
  Ding D D, Gao T, Sun O, et al. Inorg. Chem. Commun., 2015, 51:21-25 doi: 10.1016/j.inoche.2014.11.001
12. [12]
  Hu K Q, Jiang X, Wu S Q, et al. Inorg. Chem., 2015, 54(4):1206-1208 doi: 10.1021/ic502874n
13. [13]
  Yao M X, Zheng Q, Qian K, et al. Chem. Eur. J., 2013, 19(1):294-303 doi: 10.1002/chem.201203361
14. [14]
  Alexandru M G, Visinescu D, Andruh M, et al. Chem. Eur. J., 2015, 21(14):5429-5446 doi: 10.1002/chem.201406088
15. [15]
  Bridonneau N, Gontard G, Marvaud V. Dalton Trans., 2015, 44(11):5170-5178 doi: 10.1039/C4DT03757J
16. [16]
  Gheorghe R, Andruh M, Costes J P, et al. Chem. Commun., 2003(22):2778-2779 doi: 10.1039/B310082K
17. [17]
  Dhers S, Costes J P, Guionneau P, et al. Chem. Commun., 2015, 51(37):7875-7878 doi: 10.1039/C5CC01743B
18. [18]
  Visinescu D, Alexandru M G, Madalan A M, et al. Dalton Trans., 2015, 44(38):16713-16727 doi: 10.1039/C5DT01738F
19. [19]
  Visinescu D, Madalan A M, Andruh M, et al. Chem. Eur. J., 2009, 15(44):11808-11814 doi: 10.1002/chem.v15:44
20. [20]
  Alexandru M G, Visinescu D, Madalan A M, et al. Inorg. Chem., 2012, 51(9):4906-4908 doi: 10.1021/ic300544m
21. [21]
  Huang X C, Zhao X H, Shao D, et al. Dalton Trans., 2017, 46(22):7232-7241 doi: 10.1039/C7DT01167A
22. [22]
  Wang Z X, Zhang X, Zhang Y Z, et al. Angew. Chem., Int. Ed., 2014, 53(43):11567-11570 doi: 10.1002/anie.201407628
23. [23]
  Béreau V, Bolvin H, Duhayon C, et al. Eur. J. Inorg. Chem., 2016, 31:4988-4995
24. [24]
  Dhers S, Sahoo S, Costes J P, et al. CrystEngComm, 2009, 11(10):2078-2083 doi: 10.1039/b906539c
25. [25]
  Visinescu D, Alexandru M G, Madalan A M, et al. Dalton Trans., 2016, 45(18):7642-7649 doi: 10.1039/C6DT00614K
26. [26]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
27. [27]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
28. [28]
  Sun W B, Yan P F, Li G M, et al. Inorg. Chem. Commun., 2010, 13(1):171-174 doi: 10.1016/j.inoche.2009.11.006
29. [29]
  Liu M J, Hu K Q, Liu C M, et al. New J. Chem., 2016, 40(10):8643-8649 doi: 10.1039/C6NJ01887D
30. [30]
  Zhou H B, Chen C, Wu K, et al. Eur. J. Inorg. Chem., 2016(30):4921-4927
31. [31]
  Towatari M, Nishi K, Fujinami T, et al. Inorg. Chem., 2013, 52(10):6160-6178 doi: 10.1021/ic400594u
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
9. [9]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
10. [10]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
11. [11]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
12. [12]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
13. [13]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
14. [14]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
15. [15]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
16. [16]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
17. [17]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
18. [18]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
19. [19]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
20. [20]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(919)
HTML views(74)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142