Citation: LI Dong-Ping, WANG Qian, XIE Yi-Bu, ZHANG Jun, LIAN Qing-Yun, LI Yong-Xiu. Mononuclear Dy(Ⅲ) and Ho(Ⅲ) Complexes with Slow Magnetic Relaxation Behavior[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1547-1554. doi: 10.11862/CJIC.2018.170 shu

Mononuclear Dy(Ⅲ) and Ho(Ⅲ) Complexes with Slow Magnetic Relaxation Behavior

LI Dong-Ping ^1,, ,
WANG Qian ¹ ,
XIE Yi-Bu ¹ ,
ZHANG Jun ² ,
LIAN Qing-Yun ¹ ,
LI Yong-Xiu ^1,,

1.
Department of Chemistry, Nanchang University, Nanchang 330031, China
2.
Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, Hefei 230022, China

Corresponding author: LI Dong-Ping, nculdp@126.com LI Yong-Xiu, yxli@ncu.edu.cn
Received Date: 8 March 2018
Revised Date: 3 May 2018

Figures(7)

Two new lanthanide complexes based on Schiff base ligand, namely[Dy(salen)₂]₃·3C₂H₉N₂·2CH₃OH (1) and[Ho(salen)₂]₃·3C₂H₉N₂·1.5CH₃OH (2), (H₂salen=N, N'-bis(3-methoxysalicylidene)ethylene-1, 2-diamine), have been synthesized and characterized. Single-crystal X-ray diffractions reveal that 1 and 2 crystallize in the same monoclinic space group C2, and have similar coordination environment around the metallic centers. Single molecule magnets (SMMs) behaviors have been observed in 1 and 2 with/without an applied magnetic field.
- Lanthanide complex,
- crystal structure,
- single-molecule magnet
1. [1]
  Liu S S, Meng Y S, Gao S, et al. Inorg. Chem., 2017, 56(13):7320-7323 doi: 10.1021/acs.inorgchem.7b00952
2. [2]
  YANG Yu-Ting, TU Chang-Zheng, YAO Li-Feng, et al. Chinese J. Inorg. Chem., 2016, 32(8):1311-1318 doi: 10.11862/CJIC.2016.185
3. [3]
  Gregson M, Chilton N F, Ariciu A M, et al. Chem. Sci., 2016, 7(1):155-165 doi: 10.1039/C5SC03111G
4. [4]
  Peng J B, Zhang Q C, Kong X J, et al. J. Am. Chem. Soc., 2012, 134(7):3314-3317 doi: 10.1021/ja209752z
5. [5]
  Liu J L, Yuan K, Leng J D, et al. Inorg. Chem., 2012, 51(15):8538-8544 doi: 10.1021/ic301115b
6. [6]
  Magnani N, Apostolidis C, Morgenstern A, et al. Angew. Chem. Int. Ed., 2011, 50(7):1696-1698 doi: 10.1002/anie.201006619
7. [7]
  Craig G A, Murrie M. Chem. Soc. Rev., 2015, 44(8):2135-2147 doi: 10.1039/C4CS00439F
8. [8]
  Ishikawa N, Sugita M, Ishikawa T, et al. J. Am. Chem. Soc., 2003, 125(29):8694-8695 doi: 10.1021/ja029629n
9. [9]
  Das C, Upadhyay A, Vaidya S, et al. Chem. Commun., 2015, 51(28):6137-6140 doi: 10.1039/C4CC09523E
10. [10]
  Akhtar M N, Liao X F, Chen Y C, et al. Dalton Trans., 2017, 46(9):2981-2987 doi: 10.1039/C7DT00047B
11. [11]
  Rinehart J D, Meihaus K R, Long J R. J. Am. Chem. Soc., 2010, 132(22):7572-7573 doi: 10.1021/ja1009019
12. [12]
  Blagg R J, Muryn C A, McInnes E J L, et al. Angew. Chem. Int. Ed., 2011, 50(29):6530-6533 doi: 10.1002/anie.v50.29
13. [13]
  Blagg R J, Ungur L, Tuna F, et al. Nat. Chem., 2013, 5(8):673-678 doi: 10.1038/nchem.1707
14. [14]
  Woodruff D N, Winpenny R E P, Layfield R A. Chem. Rev., 2013, 113(7):5110-5148 doi: 10.1021/cr400018q
15. [15]
  Adão P, Barroso S, Avecilla F, et al. J. Organomet. Chem., 2014, 760:212-223 doi: 10.1016/j.jorganchem.2013.10.019
16. [16]
  Roy S, Drew M G B, Bauzá A, et al. CrystEngComm, 2018, 20(12):1679-1689 doi: 10.1039/C7CE01473B
17. [17]
  Kaczmarek A M, Porebski P W A, Mortier T, et al. J. Inorg. Biochem., 2016, 163:194-205 doi: 10.1016/j.jinorgbio.2016.07.017
18. [18]
  ZOU Xiao-Yan, MA Hui-Yuan, PANG Hai-Jun, et al. Chinese J. Inorg. Chem., 2016, 32(9):1647-1652
19. [19]
  Andruh M. Dalton Trans., 2015, 44(38):16633-16653
20. [20]
  Leuenberger M N, Loss D. Nature, 2001, 410(6830):789-793 doi: 10.1038/35071024
21. [21]
  Bogani L, Wernsdorfer W. Nat. Mater., 2008, 7(3):179-186 doi: 10.1038/nmat2133
22. [22]
  Mannini M, Pineider F, Sainctavit P, et al. Nat. Mater., 2009, 8(3):194-197 doi: 10.1038/nmat2374
23. [23]
  Ganzhorn M, Klyatskaya S, Ruben M, et al. Nat. Nanotechnol., 2013, 8(3):165-169 doi: 10.1038/nnano.2012.258
24. [24]
  Chen Y C, Liu J L, Ungur L, et al. J. Am. Chem. Soc., 2016, 138(8):2829-2837 doi: 10.1021/jacs.5b13584
25. [25]
  Xia H T, Liu Y F, Ma W X. J. Coord. Chem., 2013, 66(21):3706-3721 doi: 10.1080/00958972.2013.850496
26. [26]
  Costes J P, Laussac J P, Nicodème F. J. Chem. Soc. Dalton Trans., 2002(13):2731-2736 doi: 10.1039/b201136k
27. [27]
  LIU Jian, ZHANG Xiao-Peng, LI Cheng-Hui. Chinese J. Inorg. Chem., 2017, 33(11):2060-2064 doi: 10.11862/CJIC.2017.256
28. [28]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
29. [29]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
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沈阳化工大学材料科学与工程学院沈阳 110142