Citation: ZHANG Yuan-Yuan, YI Qing-Feng, LI Guang, ZHOU Xiu-Lin. Carbon Nanotube-Supported Ternary Pd-Ag-Sn Catalysts for Formic Acid Electro-Oxidation[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1209-1220. doi: 10.11862/CJIC.2018.167 shu

Carbon Nanotube-Supported Ternary Pd-Ag-Sn Catalysts for Formic Acid Electro-Oxidation

1.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China
2.
Key Laboratory of Theoretical Organic Chemistry and Functional Molecule, Ministry of Education, Xiangtan, Hunan 411201, China

Corresponding author: YI Qing-Feng, yqfyy2001@hnust.edu.cn
Received Date: 4 March 2018
Revised Date: 8 May 2018

Figures(10)

Carbon nanotube-supported Pd-based binary and ternary nanocatalysts (Pd/CNT, Pd₇Ag₃/CNT, Pd₇Sn₂/CNT, Pd₇Ag₁Sn₂/CNT, Pd₇Ag₂Sn₂/CNT and Pd₇Ag₃Sn₂/CNT) have been fabricated by the NaBH₄ reduction method. They have been characterized by using XRD, TEM and XPS techniques. The ternary Pd-Ag-Sn nanoparticles exhibit a smaller average particle size of ca. 2.3 nm compared to Pd/CNT and binary Pd-Ag (or Pd-Sn) nanoparticles. The electrocatalytic activity of these catalysts towards formic acid oxidation in both H₂SO₄ and NaOH solutions has been investigated using cyclic voltammetry (CV) and chronoamperometry (CA). In both acidic and alkaline media, the ternary Pd-Ag-Sn/CNT catalysts present higher anodic current density for formic acid oxidation than Pd/CNT and binary PdAg/CNT or PdSn/CNT catalysts. Among the prepared catalysts, the Pd₇Ag₂Sn₂/CNT catalyst displays the highest HCOOH oxidation current density of 108.8 mA·cm^-2 in 0.5 mol·L^-1 H₂SO₄ solution or 211.3 mA·cm^-2 in 1 mol·L^-1 NaOH solution, corresponding to the Pd mass current density of 1 364 or 2 640 mA·mg^-1, respectively. These currents are extremely larger than those obtained from the commercial Pd/C. Results exhibit the excellent electrocatalytic activity of the ternary Pd₇Ag₂Sn₂/CNT catalyst towards formic acid oxidation.
- Pd catalyst,
- formic acid oxidation,
- fuel cell,
- electrocatalyst
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