Citation: LIANG Li-Li, LIU Cong-Sen, ZONG Zhi-Hui, ZHANG Man-Li, ZHANG Bing-Yuan, CAO Rui, WANG Zi-Hao, PANG Miao-Miao, LI Yu-Jie, TAO Zhao-Lin. Syntheses, Crystal Structures and Antimicrobial Activities of Two Coordination Polymers Based on Bisbenzimidazole Ligands and V-Shaped Dicarboxylates[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1365-1372. doi: 10.11862/CJIC.2018.163 shu

Syntheses, Crystal Structures and Antimicrobial Activities of Two Coordination Polymers Based on Bisbenzimidazole Ligands and V-Shaped Dicarboxylates

Bengbu Medical College, Bengbu, Anhui 233030, China

Corresponding author: TAO Zhao-Lin, tao6838@163.com
Received Date: 14 February 2018
Revised Date: 30 March 2018

Figures(9)

Two coordination polymers {[Ni(bbmb)(dcpe)(H₂O)]·2H₂O}_n (1) and {[Mn₂(bbmb)(dcpe)₂(H₂O)]·1.5H₂O}_n (2) have been synthesized utilizing a linear benzimidazole ligand 4, 4'-bis(benzimidazol-1-ylmethy1)biphenyl) (bbmb) combined with a V-shaped dicarboxylates ligand 4, 4'-dicarboxydiphenyl ether (H₂dcpe). Compound 1 possesses a 2D thick layer structure with sql topology. Compound 2 possesses a 2D thick layer network with a linear tetranuclear Mn₄ cluster within the network. The in vitro antimicrobial activities showed that both compounds have effective inhibiting effects.
- benzimidazole ligand,
- crystal structure,
- antimicrobial properties,
- coordination polymers
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