Citation: ZHANG Ye-Qiong, CONG Ye, ZHANG Jing, LI Xuan-Ke, DONG Zhi-Jun, YUAN Guan-Ming. Effect of Carbonization on the Structure and Supercapacitive Performance of Pitch-Based Activated Carbon Fibers[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1430-1436. doi: 10.11862/CJIC.2018.159 shu

Effect of Carbonization on the Structure and Supercapacitive Performance of Pitch-Based Activated Carbon Fibers

1.
Wuhan University of Science and Technology, College of Chemical Engineering, Hubei Province Key Laboratory of Coal Conversion and New Carbon Materials, Wuhan 430081, China
2.
Hunan University, Hunan Province Key Laboratory of Advanced Carbon Materials and Appliced Technology, Changsha 410082, China

Corresponding author: CONG Ye, congye626@126.com LI Xuan-Ke, xkli524@sina.com
Received Date: 5 February 2018
Revised Date: 11 April 2018

Figures(7)

The porous activated carbon fibers (ACFs) were obtained by the anisotropic mesophase pitch carbon fibers carbonized at 450℃ through a simple KOH chemical activation method. In order to improve the degree of crystallinity of the ACFs, the as-prepared ACFs were modified by carbonization. The effects of carbonization temperatures on the morphology, crystallinity, pore structure and supercapacitive performances of ACFs were systematically investigated. The ACFs carbonized at 1 200℃ (ACFs-1200) electrodes exhibit excellent electrochemical performance with a specific capacity of 204 F·g^-1 at 0.1 A·g^-1, which show a capacity retention of 97.0% after 1 000 cycles. Even at 20 A·g^-1, the electrodes maintain a high specific capacity of 149 F·g^-1. The results show that the ACFs-1200 electrodes deliver ultrahigh conductivity, high rate capacity and exceptional cycle stability compared with the non-carbonized ACFs electrodes.
- activated carbon fibers,
- crystallinity,
- pore structure,
- carbonization,
- supercapacitor
1. [1]
  Vilella P C, Lira J A, Azevedo D C S, et al. Ind. Crops Prod., 2017, 109:134-140 doi: 10.1016/j.indcrop.2017.08.017
2. [2]
  Moreira R D F M, Humeres E, Berger C, et al. J. Photochem. Photobiol., B, 2017, 174:261-268 doi: 10.1016/j.jphotobiol.2017.08.001
3. [3]
  Liu Y, Zhao Y, Li K X, et al. J. Power Sources, 2018, 378:1-9 doi: 10.1016/j.jpowsour.2017.12.019
4. [4]
  LI Xin, ZHENG Feng, LUO Yuan, et al. J. Funct. Mater., 2017, 48(8):8186-8189, 8196
5. [5]
  Balogun M S, Qiu W, Wang W, et al. J. Mater. Chem. A, 2014, 3(4):1364-1387
6. [6]
  Sun F, Gao J H, Zhu Y W, et al. Sci. Rep., 2017, 7:40990-41000 doi: 10.1038/srep40990
7. [7]
  Peng L, Liang Y, Dong H W, et al. J. Power Sources, 2018, 377:151-160 doi: 10.1016/j.jpowsour.2017.12.012
8. [8]
  Guo Y, Shi Z Q, Chen M M, et al. J. Power Sources, 2014, 252:235-243 doi: 10.1016/j.jpowsour.2013.11.114
9. [9]
  Huang Y X, Peng L L, Liu Y, et al. ACS Appl. Mater. Interfaces, 2016, 8(24):15205-15215 doi: 10.1021/acsami.6b02214
10. [10]
  Shi H. Electrochim. Acta, 1996, 41(10):1633-1639 doi: 10.1016/0013-4686(95)00416-5
11. [11]
  Gao B F, Zhou H T, Chen D, et al. Appl. Surf. Sci., 2017, 420:535-541 doi: 10.1016/j.apsusc.2017.05.112
12. [12]
  Hanzawa Y, Hatori H, Yoshizawa N, et al. Carbon, 2002, 40(4):575-581 doi: 10.1016/S0008-6223(01)00150-6
13. [13]
  ZHONG Jia-Liang, GUO Feng-Jiao, MI Hong-Yu. Chinese J. Inorg. Chem., 2015, 31(11):2128-2134
14. [14]
  Xu B, Wu F, Chen S, et al. Electrochim. Acta, 2007, 52(13):4595-4598 doi: 10.1016/j.electacta.2007.01.006
15. [15]
  Su L J, Li B H, Zhao D Y, et a1. Pigm. Resin Technol., 2016, 45(3):164-171 doi: 10.1108/PRT-03-2015-0029
16. [16]
  Wang Q, Yan J, Fan Z J. Energy Environ. Sci., 2016, 9(3):729-762 doi: 10.1039/C5EE03109E
17. [17]
  Zhong C, Deng Y D, Hu W B, et al. Chem. Soc. Rev., 2015, 44(21):7484-7539 doi: 10.1039/C5CS00303B
18. [18]
  Ferrari A C, Robertson J. Phys. Rev. B:Condens. Matter, 2000, 61(20):14095-14107 doi: 10.1103/PhysRevB.61.14095
19. [19]
  Guo N N, Li M, Sun X K, et al. Mater. Chem. Phys., 2017, 201:399-407 doi: 10.1016/j.matchemphys.2017.08.054
20. [20]
  Kim S T, Coplen T B, Horita J, et al. Geochim. Cosmochim. Acta, 2015, 158(1):276-289
21. [21]
  Zheng Q F, Cai Z Y, Ma Z Q, et al. ACS Appl. Mater. Interfaces, 2015, 7(5):3263-3271 doi: 10.1021/am507999s
22. [22]
  Basri N H, Deraman M, Kanwal S, et al. Biomass Bioenergy, 2013, 59(1):370-379
23. [23]
  Wei L, Sevilla M, Fuertes A B, et al. Adv. Energy Mater., 2011, 1(3):356-361 doi: 10.1002/aenm.v1.3
24. [24]
  YU Yan-Yan, GUAN Yun-Feng, CONG Ye, et al. Chinese J. Inorg. Chem., 2017, 33(5):853-859 doi: 10.11862/CJIC.2017.085
25. [25]
  Du B, Hong C Q, Wang A Z, et al. Ceram. Int., 2018, 44(1):563-570 doi: 10.1016/j.ceramint.2017.09.212
26. [26]
  Xie X J, Gao N Y, Deng R R, et al. Acc. Chem. Res., 2012, 45(10):1759-1769 doi: 10.1021/ar300094m
27. [27]
  Wang K, Song Y, Yan R, et al. Appl. Surf. Sci., 2017, 394:569-577 doi: 10.1016/j.apsusc.2016.10.161
28. [28]
  Ma C, Wang R R, Xie Z Y, et al. J. Porous Mater., 2017, 24:1437-1445 doi: 10.1007/s10934-017-0384-3
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沈阳化工大学材料科学与工程学院沈阳 110142