Citation: YANG Jian, TAO Jia-Yu, XIN Guo-Xiang, MENG Ting, YUAN Xue-Mei, DU Li-Ting, LI Xu, XU Hai-Jun. Syntheses, Characterization and Crystal Structures of Metal Coordination Polymers Based on L-Malic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1312-1318. doi: 10.11862/CJIC.2018.157 shu

Syntheses, Characterization and Crystal Structures of Metal Coordination Polymers Based on L-Malic Acid

YANG Jian ¹ ,
TAO Jia-Yu ¹ ,
XIN Guo-Xiang ¹ ,
MENG Ting ¹ ,
YUAN Xue-Mei ¹ ,
DU Li-Ting ² ,
LI Xu ² ,
XU Hai-Jun ^1,,

1.
College of Chemical Engineering, Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037, China
2.
College of Science, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: XU Hai-Jun, xuhaijun@njfu.edu.cn
Received Date: 2 February 2018
Revised Date: 3 May 2018

Figures(4)

Three metal-organic coordination polymers, namely[{Zn(mal)(2, 2'-bipy)]₂·5H₂O}_n (1), {[Zn(mal)(Phen)(H₂O)]₂·3H₂O}_n (2) and {[Cu(mal)(Phen)]₂·4H₂O}_n (3) (H₂mal=L-malic acid, 2, 2'-bipy=2, 2'-bipyridine, Phen=phenanthroline), have been synthesized by the reaction of Zn(CH₃CO₂)₂·2H₂O or CuCl₂ with L-malic acid and cooperative ligand (2, 2'-bipy, Phen) in solution, respectively. They were characterized by powder and single X-ray diffraction analysis, FTIR spectroscopy and elemental analysis. Single crystal X-ray analysis reveals that complexes 1, and 2 crystallize in orthorhombic system with space group P2₁2₁2₁. In complexes 1 and 2, the two adjacent metal atoms are bridged by one malate group, constructing a one-dimensional zigzag chain, and two parallel 1D chains are constituted to form a novel ladder double chain structure through π-π weak interaction between the pyridine or phenanthroline rings. However, complex 3 crystallizes in monoclinic system with space group P2₁ and copper centers are also bridged by malate group, which is linked into one dimensional chain and self-assembled to form two dimensional lamellar supramolecular architectures through weak π-π interaction between the phenanthroline rings.
- coordination polymer,
- L-malic acid,
- bipyridine,
- phenanthroline
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