Citation: TANG Sheng-Yang, MI Chang-Huan, WANG Jie. A Hybrid Aqueous Full Battery Based on LiMn₂O₄ Cathode and NaTi₂(PO₄)₃ Anode[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1279-1284. doi: 10.11862/CJIC.2018.155 shu

A Hybrid Aqueous Full Battery Based on LiMn₂O₄ Cathode and NaTi₂(PO₄)₃ Anode

Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Corresponding author: MI Chang-Huan, mchmse@nuaa.edu.cn
Received Date: 17 January 2018
Revised Date: 29 April 2018

Figures(7)

A new aqueous full battery based on LiMn₂O₄ cathode and NaTi₂(PO₄)₃ anode with the hybrid ion electrolytes (1 mol·L^-1 Li₂SO₄+0.5 mol·L^-1 Na₂SO₄) was presented. The electrochemical performances of LiMn₂O₄ and NaTi₂(PO₄)₃ in the different aqueous electrolytes (1 mol·L^-1 Li₂SO₄, 0.5 mol·L^-1 Na₂SO₄ and 1 mol·L^-1 Li₂SO₄+0.5 mol·L^-1 Na₂SO₄) were characterized by the cyclic voltammetry (1 mV·s^-1) and the galvanostatic charge/discharge (265 mA·g^-1). The results show that Li⁺ ion could de-intercalation/intercalation from/into LiMn₂O₄ but Na⁺ could not because of its larger radius, and both ions (Li⁺ and Na⁺) could intercalation/de-intercalation into/from NaTi₂(PO₄)₃. The charge and discharge specific capacity was 100.1 and 74.9 mAh·g^-1, respectively, with a higher discharge voltage (1.55 V) for this aqueous full battery.
- aqueous full battery,
- hybrid ion electrolytes,
- high voltage,
- electrochemical performance,
- cyclic voltammetry
1. [1]
  Hu M, Pang X L, Zhou Z. J. Power Sources, 2013, 237(3):229-242
2. [2]
  Patoux S, Daniel L, Bourbon C, et al. J. Power Sources, 2009, 189(1):344-352 doi: 10.1016/j.jpowsour.2008.08.043
3. [3]
  Sun J, Li J G, Zhou T, et al. Nano Energy, 2016, 27:313-319 doi: 10.1016/j.nanoen.2016.06.031
4. [4]
  HUANG Yu-Dai, LI Juan, JIA Dian-Zeng. Chinese J. Inorg. Chem., 2004, 20(7):837-840
5. [5]
  Wang Y G, Xia Y Y. Electrochem. Commun., 2005, 7:1138-1142 doi: 10.1016/j.elecom.2005.08.017
6. [6]
  Luo J Y, Xia Y Y. Adv. Funct. Mater., 2007, 17:3877-3884 doi: 10.1002/(ISSN)1616-3028
7. [7]
  YI Jin, WANG Yong-Gang, XIA Yong-Yao. Chin. Sci. Bull., 2013, 58:3274-3286
8. [8]
  Sathiyaraj K, Akanksha P, Manickam M. Electrochim. Acta, 2012, 60:170-176 doi: 10.1016/j.electacta.2011.11.028
9. [9]
  ZHANG Chuan-Xiang, HE Jian-Ping, ZHAO Gui-Wang, et al. Chinese J. Inorg. Chem., 2007, 23(4):649-654
10. [10]
  Zhao M S, Huang G L, Wang F, et al. Electrochim. Acta, 2015, 151:50-55 doi: 10.1016/j.electacta.2014.10.148
11. [11]
  ZHANG Ning, LIU Yong-Chang, CHEN Cheng-Cheng et al. Chinese J. Inorg. Chem., 2015, 31(9):1739-1750
12. [12]
  Zhang Q, Liao C Y, Zhai T Y, et al. Electrochim. Acta, 2016, 196:470-478 doi: 10.1016/j.electacta.2016.03.007
13. [13]
  Li Z, David Y, Xiang K, et al. Adv. Energy Mater., 2013, 3:290-294 doi: 10.1002/aenm.v3.3
14. [14]
  Wu X Y, Cao L Y, Ai X P, et al. Electrochem. Commun., 2013, 31:145-148 doi: 10.1016/j.elecom.2013.03.013
15. [15]
16. [16]
  Qu Q T, Shi Y, Tian S, et al. J. Power Sources, 2009, 194(2):1222-1225 doi: 10.1016/j.jpowsour.2009.06.068
17. [17]
  Chen L, Gu Q W, Zhou X F, et al. Sci. Rep., 2013, 3(6):1946(7 Pages)
18. [18]
  Chen L, Zhang L Y, Zhou X F, et al. ChemSuschem, 2014, 7(8):2295-2302 doi: 10.1002/cssc.201402084
19. [19]
  Chen L, Shao H Z, Zhou X F, et al. Nat. Commun., 2016, 7:11928(10 Pages)
20. [20]
  Nulati Y, Nurzhan U, Aibolat K, et al. Electrochim. Acta, 2015, 152:505-511 doi: 10.1016/j.electacta.2014.11.168
21. [21]
  Wu X W, Li Y H, Xiang Y H, et al. J. Power Sources, 2016, 336:35-39 doi: 10.1016/j.jpowsour.2016.10.053
22. [22]
  Shyue P O, Vincent L, Geoffroy H, et al. Energy Environ. Sci., 2011, 4:3680-3688 doi: 10.1039/c1ee01782a
23. [23]
  Eiji H, Tetsuichi K, Itaru H, et al. Nano Lett., 2009, 9:1045-1051 doi: 10.1021/nl803394v
24. [24]
  Chen L, Liu J Y, Guo Z W, et al. J. Electrochem. Soc., 2016, 163:A904-A910 doi: 10.1149/2.0531606jes
25. [25]
  Li N C, Patrissi C, Che G, et al. J. Electrochem. Soc., 2000, 147(6):2044-2049 doi: 10.1149/1.1393483
26. [26]
  Tang W, Zhu Y S, Hou Y Y, et al. Energy Environ. Sci., 2013, 6:2093-2104 doi: 10.1039/c3ee24249h
27. [27]
  Delmas C, Nadiri A, Soubeyroux J L. Solid State Ionics, 1988, 28-30(Part 1):419-423
28. [28]
  Sun D, Jin G, Tang Y, et al. J. Electrochem. Soc., 2016, 163(7):A1388-A1393 doi: 10.1149/2.1181607jes
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A Hybrid Aqueous Full Battery Based on LiMn₂O₄ Cathode and NaTi₂(PO₄)₃ Anode