Citation: ZHOU Xin, ZHANG Mei-Na, ZHANG De-Chun, LI Xia, YAO Ying-Fang. Syntheses, Crystal Structures and Fluorescence Sensing of Lanthanide Complexes with 3, 4'-Biphenyldicarboxylic Acid and N-donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1285-1292. doi: 10.11862/CJIC.2018.153 shu

Syntheses, Crystal Structures and Fluorescence Sensing of Lanthanide Complexes with 3, 4'-Biphenyldicarboxylic Acid and N-donor Ligands

Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: LI Xia, xiali@mail.cnu.edu.cn
Received Date: 25 January 2018
Revised Date: 2 April 2018

Figures(6)

Two lanthanide complexes, [Gd(3, 4'-dpdc)₂(HDPP)]_n (1) and {[Dy(3, 4'-Hdpdc)₃(H₂O)]·0.5BTB}_n (2) (3, 4'-H₂dpdc=3, 4'-biphenyldicarboxylic acid, DPP=1, 3-bis(4-pyridyl)propane, BTB=1, 4-bis(1, 2, 4-triazol-1-yl)butane) were successfully synthesized under hydrothermal reactions, and their structures were characterized by single crystal X-ray diffraction. Complex 1 belongs to monoclinic system, space group P2₁/c. It is two-dimensional layered structure and consists of[GdO₇N] unit. 3, 4'-dpdc ligands are connected to the Gd(Ⅲ) ions by μ₁:η¹η¹/μ₂:η¹η¹ and μ₁:η¹η¹/μ₁:η¹η⁰ coordination modes. DPP ligands are end-coordinated to Gd(Ⅲ) ions. Complex 2 is a triclinic system, space group P1. The complex shows a one-dimensional chain structure. The coordination environment of Dy(Ⅲ) ion is[DyO₇]. The 3, 4'-Hdpdc ligands link Dy(Ⅲ) ions in a μ₂:η¹η¹ coordination mode. The BTB molecules are connected to the one-dimensional chains by hydrogen bonds and thus form a three-dimensional supramolecular structure. Solid state photoluminescence measurements show that compounds 1 and 2 display broad band in the range of 350~650 nm due to the π^*→π transition of the ligands. The effect of different floxacins on the luminescence of complex 1 in aqueous solution was studied. The results showed that the complex could identify pefloxacin.
- lanthanide complex,
- 3, 4'-biphenyldicarboxylic acid,
- crystal structure,
- fluorescence
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