Citation: YAO Xun, LI Ming-Gao, XIE Yan-Chun, LIU Fei, LIU Qin, LIU Yang, LI Peng, XUE Rui-Ting, FAN Xi-Mei. Fabrication and Photocatalytic Properties of Hollow Sphere Cu₂O with Different Surface Morphology[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1086-1094. doi: 10.11862/CJIC.2018.144 shu

Fabrication and Photocatalytic Properties of Hollow Sphere Cu₂O with Different Surface Morphology

YAO Xun ¹ ,
LI Ming-Gao ^2,, ,
XIE Yan-Chun ¹ ,
LIU Fei ¹ ,
LIU Qin ¹ ,
LIU Yang ¹ ,
LI Peng ¹ ,
XUE Rui-Ting ¹ ,
FAN Xi-Mei ^1,,

1.
Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
2.
CRRC Institute Co., Ltd., Beijng 100070, China

Corresponding author: LI Ming-Gao, lmg0520@126.com FAN Xi-Mei, fanximei@126.com
Received Date: 15 January 2018
Revised Date: 15 April 2018

Figures(15)

The shape-controlled hollow sphere Cu₂O nanomaterials were prepared by one-step solvothermal method, and used Cu(NO₃)₂·3H₂O as raw material, ethylene glycol as reductant and polyvinylpyrrolidone (PVP) as surfactant. In this study, the influence of different mass ratios of Cu(NO₃)₂·3H₂O and PVP (w_{Cu(NO₃)₂·3H₂O}/w_PVP) and reaction time on the crystal structures, morphologies, surface area and optical properties of Cu₂O was researched. The photocatalytic mechanism of Cu₂O nanocrystals are also investigated. The results show that the photocatalytic activity of Cu₂O hollow spheres covered by nano-thorns is best when w_{Cu(NO₃)₂·3H₂O}/w_PVP=45, and at the 1 h of irradiation, the photodegradation efficiency of methyl orange solution can reach up to 94.3%.
- shape-controlled,
- hollow sphere,
- Cu₂O nanomaterials,
- photocatalytic property
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Fabrication and Photocatalytic Properties of Hollow Sphere Cu₂O with Different Surface Morphology