Citation: LI Yu, ZOU Xun-Zhong, GU Jin-Zhong, CHENG Xiao-Ling. Syntheses, Crystal Structures and Magnetic Properties of Two Copper(Ⅱ) and Manganese(Ⅱ) Coordination Compounds Constructed from Biphenyl Tricarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1159-1165. doi: 10.11862/CJIC.2018.142 shu

Syntheses, Crystal Structures and Magnetic Properties of Two Copper(Ⅱ) and Manganese(Ⅱ) Coordination Compounds Constructed from Biphenyl Tricarboxylic Acid

1.
School of Eco-Environmental Engineering, Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
3.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

Corresponding author: GU Jin-Zhong, gujzh@lzu.edu.cn CHENG Xiao-Ling, ggcxl@163.com
Received Date: 2 January 2018
Revised Date: 24 March 2018

Figures(10)

Zero dimensional dinuclear copper(Ⅱ) coordination compound and 3D manganese(Ⅱ) coordination polymer, namely[Cu₂(Hdppa)₂(4, 4'-bipy)(H₂O)₄]·4, 4'-bipy·6H₂O (1) and {[Mn₃(μ₅-dppa)₂(4, 4'-bipy)(H₂O)₂]·4H₂O}_n (2), have been constructed hydrothermally using H₃dppa, 4, 4'-bipy (H₃dppa=5-(3, 4-dicarboxylphenyl)picolinic acid, 4, 4'-bipy=4, 4'-bipyridine), and copper or manganese chlorides. Single-crystal X-ray diffraction analyses revealed that two compounds crystallize in the triclinic or monoclinic system, space group P1 or C2/c. In compound 1, one 4, 4'-bipy ligand bridges neighboring Cu(Ⅱ) ions to form a discrete dinuclear copper(Ⅱ) structure. These Cu₂ units are assembled to a 3D supramolecular framework through O-H…O/N hydrogen bond. In compound 2, neighboring Mn(Ⅱ) ions are bridged by the carboxylate groups of μ₅-dppa^3- ligands, producing a double-helix Mn(Ⅱ) chain subunit. The adjacent double-helix chains subunits are further linked by the dppa^3- blocks and 4, 4'-bipy ligands into a 3D framework. Magnetic studies for compound 2 demonstrate an antiferromagnetic coupling between the adjacent Mn(Ⅱ) centers.
- coordination polymer,
- hydrogen bonding,
- tricarboxylic acid,
- magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142