Citation: LIU Qiang, ZHANG Shuai, DU Kai, YIN Qiang, LI Wa, CAI Pei-Jun. Syntheses, Crystal Structures and Luminescence Properties of Nd Complexes with β-Diketonate and Triphenylphosphine Oxide[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1143-1148. doi: 10.11862/CJIC.2018.141 shu

Syntheses, Crystal Structures and Luminescence Properties of Nd Complexes with β-Diketonate and Triphenylphosphine Oxide

LIU Qiang ^1,2,3 ,
ZHANG Shuai ³ ,
DU Kai ³ ,
YIN Qiang ³ ,
LI Wa ³ ,
CAI Pei-Jun ^1,,

1.
School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
2.
College of Arts and Science, Jilin Agricultural Science and Technology University, Jilin, Jilin 132101, China
3.
Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, Sichuan 621900, China

Corresponding author: CAI Pei-Jun, caipj@163.com
Received Date: 6 December 2017
Revised Date: 27 March 2018

Figures(6)

Two ternary complexes of neodymium ions, [Nd(TTA)₃(TPPO)₂] (1) and[Nd(BFA)₃(TPPO)₂] (2), based on 4, 4, 4-trifluoro-1-(2-thienyl)-1, 3-butanedione(TTA), 4, 4, 4-trifluoro-1-phenyl-1, 3-butanedione(BFA) and triphenyl-phosphineoxide(TPPO) have been synthesized by mild condition and the single crystals suitable for X-ray measurement were obtained. The structures of the two Nd complexes were determined in solid states by X-ray diffraction. Single crystal analysis revealed that the complexes are both eight-coordinated with one center Nd ion and eight O atoms from ligands and crystallize in triclinic symmetry with P1 space group. The complexes were characterized by elemental analysis, IR spectroscopy and thermogravimetric. Furthermore, photophysical studies on the complexes were carried out, which shows luminescence in near-infrared area.
- neodymium complex,
- synthesis,
- crystal structure,
- luminescence property
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沈阳化工大学材料科学与工程学院沈阳 110142