Citation: WANG Yu-Fang, TAI Jun-Hui, YAN Xiao-Wei, ZHAO Meng-Yun, WANG Li-Ya. Crystal Structures and Magnetic Properties of Two Isomorphic Frameworks Based on 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1, 2, 4-triazole and 1, 2, 4, 5-Benzenetetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1121-1126. doi: 10.11862/CJIC.2018.135 shu

Crystal Structures and Magnetic Properties of Two Isomorphic Frameworks Based on 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1, 2, 4-triazole and 1, 2, 4, 5-Benzenetetracarboxylic Acid

1.
College of Chemistry and Chemical Engineering, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang, Henan 471934, China
2.
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473000, China

Corresponding author: WANG Yu-Fang, wangyf78@163.com
Received Date: 19 October 2017
Revised Date: 27 March 2018

Figures(5)

Two new isomorphic coordination polymers, [M(btec)_0.5(H₂L)]_n (M=Co(Ⅱ) (1), Cu(Ⅱ) (2); H₄btec=1, 2, 4, 5-benzenetetracarboxylic acid; H₂L=3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1, 2, 4-triazole), have been synthesized under hydrothermal conditions. Compounds 1 and 2 were structurally characterized by elemental analysis, single crystal X-ray diffraction analysis, infrared spectroscopy and powder X-ray diffraction analysis. Single crystal X-ray diffraction measurement reveals that compounds 1 and 2 are isostructural structure and all crystallize in the orthorhombic system, space group Pbca. Compounds 1 and 2 have same 2D structure, which are connected by N…H…O hydrogen bonds to generate 3D frameworks. In addition, magnetic studies indicate that 1 show weak ferromagnetic exchange through carboxylate bridges between metal ions, and there is typical paramagnetic behavior in 2.
- isomorphic,
- crystal structure,
- magnetic property
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1.
沈阳化工大学材料科学与工程学院沈阳 110142