Citation: CHENG Lin, LIU Qi, YANG Jing-Hua, ZHANG Qing-Song. Anion-Induced Chiral Cu(Ⅱ) Coordination Polymers: Reversible Structural Transformation, CD Spectra and SHG Response[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1018-1027. doi: 10.11862/CJIC.2018.134 shu

Anion-Induced Chiral Cu(Ⅱ) Coordination Polymers: Reversible Structural Transformation, CD Spectra and SHG Response

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: CHENG Lin, lcheng@seu.edu.cn
Received Date: 11 January 2018
Revised Date: 31 January 2018

Figures(10)

Two new chiral Cu(Ⅱ) coordination polymers, {[Cu((1R, 2R)-3-bcpb)]Cl₂}_n (1) and {[Cu((1R, 2R)-3-bcpb)₂](ClO₄)₂·2H₂O·2CH₃OH}_n (2) ((1R, 2R)-3-bcpb=N, N'-((1R, 2R)-cyclohexane-1, 2-diyl)bis(N-(pyridin-3-ylmethyl)benz-amide)), have been assembled with a chiral V-shaped bidentate ligand and different Cu(Ⅱ) salts, in which 1 is a 1D linear chain, while 2 displays a 2D (4, 4) topology. 1 can be directly transformed to 2 by the introduction of AgClO₄, and 2 can also be directly converted to 1 by the addition of NaCl in methanol under solvothermal conditions. CD spectra and SHG response of the complexes confirm that their bulk samples are both of structural chirality.
- chiral coordination polymers,
- reversible structural transformation,
- chiral 1, 2-diaminocyclohexane,
- anion-induced
1. [1]
  Bradshaw D, Claridge J B, Cussen E J, et al. Acc. Chem. Res., 2005, 38:273-282 doi: 10.1021/ar0401606
2. [2]
  Crassous J. Chem. Soc. Rev., 2009, 38:830-845 doi: 10.1039/b806203j
3. [3]
  CHEN Li-Zhuang, CAO Xing-Xing, WANG Fang-Ming, et al. Chinese J. Inorg. Chem., 2012, 28(6):1291-1297
4. [4]
  Zhang J, Chen S M, Wu T, et al. J. Am. Chem. Soc., 2008, 130:12882-12883 doi: 10.1021/ja805272j
5. [5]
  Xia Q C, Li Z J, Tan C X, et al. J. Am. Chem. Soc., 2017, 139:8259-8266 doi: 10.1021/jacs.7b03113
6. [6]
  JI Qin, CHEN Li-Zhuang. Chinese J. Inorg. Chem., 2017, 33(5):874-880 doi: 10.11862/CJIC.2017.099
7. [7]
  SHI Feng-Xiang, WU Wen-Shi, HUANG Miao-Ling. Chinese J. Inorg. Chem., 2016, 32(8):1327-1336 doi: 10.11862/CJIC.2016.171
8. [8]
  Mon M, Ferrando-Soria J, Verdaguer M, et al. J. Am. Chem. Soc., 2017, 139:8098-8101 doi: 10.1021/jacs.7b03633
9. [9]
  XU Zhong-Xuan. Chem. J. Chinese Universities, 2017, 38(10):1724-1729 doi: 10.7503/cjcu20170066
10. [10]
  WANG Ping-Ping, CHEN Dan-Ping, WANG Shu-Hua, et al. Chinese J. Inorg. Chem., 2017, 33(5):817-822 doi: 10.11862/CJIC.2017.095
11. [11]
  Song B Q, Chen D Q, Ji Z G, et al. Chem. Commun., 2017, 53:1892-1895 doi: 10.1039/C6CC07729C
12. [12]
  Yang Z W, Zhu C F, Li Z J, et al. Chem. Commun., 2014, 50:8775-8778 doi: 10.1039/C4CC03308F
13. [13]
  Lin S Y, Wang C, Zhao L, et al. Chem. Asian J., 2014, 9:3558-3564 doi: 10.1002/asia.v9.12
14. [14]
  Zhang D P, Zhuo S P, Zhang H Y, et al. Dalton Trans., 2015, 44:4655-4664 doi: 10.1039/C4DT03274H
15. [15]
  Cheng L, Zhang L M, Gou S H, et al. CrystEngComm, 2012, 14:3888-3893 doi: 10.1039/c2ce25043h
16. [16]
  Cheng L, Zhang L M, Gou S H, et al. CrystEngComm, 2012, 14:4437-4443 doi: 10.1039/c2ce25317h
17. [17]
  Cheng L, Zhang L M, Cao Q N, et al. CrystEngComm, 2012, 14:7502-7510 doi: 10.1039/c2ce26198g
18. [18]
  Cheng L, Cao Q N, Zhang X Y, et al. Inorg. Chem. Commun., 2012, 24:110-113 doi: 10.1016/j.inoche.2012.08.018
19. [19]
  Cheng L, Cao Q N, Zhang L M, et al. Solid State Sci., 2013, 16:34-38 doi: 10.1016/j.solidstatesciences.2012.10.016
20. [20]
  Zhang X Y, Cheng L, Wang J, et al. Inorg. Chem. Commun., 2014, 40:97-102 doi: 10.1016/j.inoche.2013.11.044
21. [21]
  Cheng L, Wang J, Zhang X Y, et al. Inorg. Chem. Commun., 2014, 47:144-147 doi: 10.1016/j.inoche.2014.07.032
22. [22]
  Cheng L, Wang J, Qi Q, et al. CrystEngComm, 2014, 16:10056-10065 doi: 10.1039/C4CE01601G
23. [23]
  Cheng L, Wang J, Yu H Y, et al. J. Solid State Chem., 2015, 221:85-94 doi: 10.1016/j.jssc.2014.09.020
24. [24]
  Wang J, Qi Q, Cheng L, et al. Inorg. Chem. Commun., 2015, 58:5-8 doi: 10.1016/j.inoche.2015.05.013
25. [25]
  Hou S, Liu Q K, Ma J P, et al. Inorg. Chem., 2013, 52:3225-3235 doi: 10.1021/ic302716n
26. [26]
  ZHANG Qi-Long. Chinese J. Inorg. Chem., 2015, 31(11):2213-2220
27. [27]
  MA De-Yun, LI Xiang, GUO Hai-Fu, et al. Chinese J. Inorg. Chem., 2017, 33(7):1266-1272 doi: 10.11862/CJIC.2017.162
28. [28]
  Kolea G K, Vittal J J. Chem. Soc. Rev., 2013, 42:1755-1775 doi: 10.1039/C2CS35234F
29. [29]
  Zhang J P, Liao P Q, Zhou H L, et al. Chem. Soc. Rev., 2014, 43:5789-5814 doi: 10.1039/C4CS00129J
30. [30]
  Khlobystov A N, Champness N R, Roberts C J, et al. CrystEngComm, 2002, 4:426-431 doi: 10.1039/B202217F
31. [31]
  Sarkar M, Biradha K. Cryst. Growth Des., 2006, 6:1742-1745 doi: 10.1021/cg060216y
32. [32]
  Heo J, Jeon Y M, Mirkin C A. J. Am. Chem. Soc., 2007, 129:7712-7713 doi: 10.1021/ja0716812
33. [33]
  Ramírez J, Stadler A M, Kyritsakasb N, et al. Chem. Commun., 2007, 43:237-239
34. [34]
  Wang Y, Cheng P, Song Y, et al. Chem. Eur. J., 2007, 13:8131-8138 doi: 10.1002/(ISSN)1521-3765
35. [35]
  Sarkar M, Biradha K. Cryst. Growth Des., 2007, 7:1318-1331 doi: 10.1021/cg070100h
36. [36]
  Cui X, Marsh D H, Blake A J, et al. Chem. Eur. J., 2009, 15:8861-8873 doi: 10.1002/chem.v15:35
37. [37]
  Yang H Y, Li L K, Wu J, et al. Chem. Eur. J., 2009, 15:4049-4056 doi: 10.1002/chem.v15:16
38. [38]
  Yi X Y, Fang H C, Gu Z G, et al. Cryst. Growth Des., 2011, 11:2824-2828 doi: 10.1021/cg101618n
39. [39]
  Lü H J, Mu Y J, Li J P, et al. Inorg. Chim. Acta, 2012, 387:450-454 doi: 10.1016/j.ica.2012.01.022
40. [40]
  Colinas I R, Inglis K K, Blanc F, et al. Dalton Trans., 2017, 46:5320-5325 doi: 10.1039/C7DT00475C
41. [41]
  Hou S S, Huang X, Gou J G, et al. CrystEngComm, 2015, 17:947-959 doi: 10.1039/C4CE01779J
42. [42]
  Ren C X, Zheng A L, Cai L X, et al. CrystEngComm, 2014, 16:1038-1043 doi: 10.1039/C3CE42164C
43. [43]
  Cai S L, Pan M, Zheng S R, et al. CrystEngComm, 2012, 14:2308-2315 doi: 10.1039/c2ce06129e
44. [44]
  Li C P, Zhou H, Mu Y H, et al. Cryst. Growth Des., 2017, 17:2024-2033 doi: 10.1021/acs.cgd.7b00020
45. [45]
  Kole G K, Vittal J J. Chem. Soc. Rev., 2013, 42:1755-1775 doi: 10.1039/C2CS35234F
46. [46]
  Zhang J J, Day C S, Lachgar A. CrystEngComm, 2011, 13:133-137 doi: 10.1039/C004119J
47. [47]
  Hou S S, Huang X, Guo J G, et al. CrystEngComm, 2015, 17:947-959 doi: 10.1039/C4CE01779J
48. [48]
  Wu X R, Yang X, Wei R J, et al. Cryst. Growth Des., 2014, 14:4891-4894 doi: 10.1021/cg5011506
49. [49]
  Chandrasekhar P, Bajpai A, Savitha G, et al. Eur. J. Inorg. Chem., 2017:1163-1170
50. [50]
  Chen S C, Tian F, Huang K L, et al. CrystEngComm, 2014, 16:7673-7680 doi: 10.1039/C4CE01019A
51. [51]
  Wardana F Y, Ng S W, Wibowo A C. Cryst. Growth Des., 2015, 15:5930-5938 doi: 10.1021/acs.cgd.5b01392
52. [52]
  Zhang H, Yang J, Liu Y Y, et al. Cryst. Growth Des., 2016, 16:3244-3255 doi: 10.1021/acs.cgd.6b00213
53. [53]
  Narang S, Singh U P, Venugopalan P. CrystEngComm, 2016, 18:54-61 doi: 10.1039/C5CE01594D
54. [54]
  Chhetri P M, Yang X K, Chen J D. Cryst. Growth Des., 2017, 17:4801-4809 doi: 10.1021/acs.cgd.7b00742
55. [55]
  Chan T W, Zhan S Z, Razali M R. New J. Chem., 2017, 41:7598-7606 doi: 10.1039/C7NJ01552F
56. [56]
  Bhattacharya S, Bhattacharyya A J, Natarajan S. Inorg. Chem., 2015, 54:1254-1271 doi: 10.1021/ic5018517
57. [57]
  Li X J, Yu Z J, Li X X, et al. Chem. Eur. J., 2015, 21:16593-16600 doi: 10.1002/chem.v21.46
58. [58]
  Michaelides A, Skoulika S. J. Mol. Struct., 2017, 1143:65-71 doi: 10.1016/j.molstruc.2017.03.127
59. [59]
  Chen Y M, Gao Q, Gao D D, et al. Chem. Asian J., 2015, 10:411-421 doi: 10.1002/asia.v10.2
60. [60]
  Dong H Z, Yang J, Liu X, et al. Inorg. Chem., 2008, 47:2913-3915 doi: 10.1021/ic702157r
61. [61]
  Li X X, Gong Y Q, Zhao H X, et al. CrystEngComm, 2014, 16:8818-8824 doi: 10.1039/C4CE01035C
62. [62]
  Zheng S R, Yin S Y, Pan M, et al. Inorg. Chem. Commun., 2015, 55:116-119 doi: 10.1016/j.inoche.2015.03.022
63. [63]
  Sheldrick G M. SADABS 2.05, University of Göttingen, Germany, 2002.
64. [64]
  SHELXTL 6.10, Bruker Analytical Instrumentation, Madison, Wisconsin, USA, 2000.
65. [65]
  Flack H D. Acta Crystallogr. Sect. A:Found. Crystallogr., 1983, A39:876-881
66. [66]
  Wang C, Zhang T, Lin W. Chem. Rev., 2012, 112:1084-1104 doi: 10.1021/cr200252n
67. [67]
  Zhang W, Xiong R G. Chem. Rev., 2012, 112:1163-1195 doi: 10.1021/cr200174w
68. [68]
  Kurtz S K, Perry T T. J. Appl. Phys., 1968, 39:3798-3813 doi: 10.1063/1.1656857
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