Citation: HUANG Yun, MA Ruo-Nan, ZENG Xian-Zhe, XIANG Ming-Xue, CUI Xi-Jun, ZHANG Ping. Preparation by Using Soft Template and Adsorption Properties of Three-Dimensional Flower-like MgAl-LDH[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 925-932. doi: 10.11862/CJIC.2018.132 shu

Preparation by Using Soft Template and Adsorption Properties of Three-Dimensional Flower-like MgAl-LDH

1.
Key Laboratory of Poyang Lake Environment and Resource Utilization(Ministry of Education), School of Environmental and Chemical Engineering, Nanchang University, Nanchang 330031, China
2.
Environmental Testing Center of Nanchang University, Nanchang 330031, China

Corresponding author: ZHANG Ping, zhangping@ncu.edu.cn
Received Date: 4 January 2018
Revised Date: 21 March 2018

Figures(10)

Three-dimensional flower-like LDH (3D-MgAl LDH) microspheres were successfully synthesized via hydrothermal method. The sodium dodecylsulfate was used as soft template. The effect of Mg/Al mole ratio, the concentration of SDS and the reaction time on the crystallinity, composition and morphology of 3D-MgAl LDH were investigated by XRD, FT-IR, SEM and TEM. The results show that the optimal condition for uniform 3D-MgAl LDH microspheres with high crystallinity, regular flower-like morphology and thickness uniformity of nanosheets are as follows, n_Mg/n_Al=2, the concentration of SDS was 0.1 mol·L^-1, and reaction time of 6 h. In addition, the growth mechanism of 3D-MgAl LDH was also inferred, SDS was used for intercalated anion to form LDH as well as could form micelles that bond to the outside surfaces and plate edges of LDH, which induced LDH nanosheet cross-growth. Finally, the adsorption activity present that 3D-MgAl LDH exhibits great adsorption capacity of ca. 30 mg·g^-1 for naphthalene and the removal rate of 100%.
- three-dimensional flower-like,
- Mg-Al LDH,
- soft template,
- adsorption,
- naphthalene
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沈阳化工大学材料科学与工程学院沈阳 110142