Citation: BA Dan, WU Wen-Shi, HUANG Miao-Ling, SHI Feng-Xiang. Syntheses, Crystal structures and Properties of Zinc Complexes Constructed with Isoquinoline Hydrazine[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 897-905. doi: 10.11862/CJIC.2018.129 shu

Syntheses, Crystal structures and Properties of Zinc Complexes Constructed with Isoquinoline Hydrazine

College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361000, China

Corresponding author: WU Wen-Shi, wws@hqu.edu.cn
Received Date: 23 November 2017
Revised Date: 24 March 2018

Figures(6)

Two new metal-organic complex, [Zn(eiqnthz)₂]·DMF (1) and[Zn₃(piqnthz)₂Cl₂]·2H₂O (2) (Heiqnthz=N, N'-acetyl isoquinoline hydrazine, H₂Piqnthz=N, N'-propionyl isoquinoline hydrazine), has been synthesized by common solution method. The structures and properties of complexes 1 and 2 are determined and characterized by single-crystal X-ray analysis, XRD powder diffraction analysis, infrared spectroscopy, thermal stability analysis and fluorescence analysis method. The crystal structural analysis revealed that the complex 1 crystalizes in monoclinic, space group C2/c, with 4 nitrogen atoms and 2 oxygen atoms from two ligands to forming a N₄O₂ distorted octahedral coordination geometry around the zinc ions. The complex 2 belongs to monoclinic system, space group C2/c as a three nuclear structure. Zn(1), Zn(2), Zn(3) ions are penta-coordinated, and the whole molecule presents V shape. Zn(1) and Zn(3) are located at both ends of the molecule and deformed tetragonal pyramidal coordination structures. Zn(2) is located in the middle to form a triangular bipyramid coordination structure. The fluorescence spectroscopic analysis demonstrated that Heiqnthz and H₂piqnthz have red-shifted phenomenon after coordinated with zinc(Ⅱ) ion.
- isoquinoline derivatives,
- zinc complexes,
- crystal structures,
- fluorescence properties,
- electronic structures
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