Citation: WANG You-He, SUN Hong-Man, Peng PENG, BAI Peng, YAN Zi-Feng, Subhan Fazle, JI Sheng-Fu. Synthesis of Hierarchical ZSM-5 Zeolites via Two Stage Varying Temperature Crystallization with Enhanced Catalytic Cracking Performance[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 989-996. doi: 10.11862/CJIC.2018.124 shu

Synthesis of Hierarchical ZSM-5 Zeolites via Two Stage Varying Temperature Crystallization with Enhanced Catalytic Cracking Performance

WANG You-He ^1,2 ,
SUN Hong-Man ^2,3 ,
Peng PENG ² ,
BAI Peng ² ,
YAN Zi-Feng ^2,, ,
Subhan Fazle ^2,4 ,
JI Sheng-Fu ^1,,

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
2.
State Key Laboratory for Heavy Oil Processing, China University of Petroleum, Qingdao, Shandong 266580, China
3.
School of Engineering and Computer Sciences, University of Hull, Hull HU6 7RX, UK
4.
Department of Chemistry, Abdul Wali Khan University Mardan, K. P., Pakistan

Corresponding author: YAN Zi-Feng, jisf@mail.buct.edu.cn JI Sheng-Fu, zfyancat@upc.edu.cn
Received Date: 10 December 2017
Revised Date: 19 March 2018

Figures(6)

Hierarchical ZSM-5 zeolites with regular spherical structure were successfully synthesized via a facile two stage varying temperature crystallization using tetrapropylammonium hydroxide (TPAOH) as the single template. The fabricated samples were characterized by means of XRD, FT-IR, NH₃-TPD, SEM, TEM and N₂ adsorption-desorption isotherms. The results indicate that the spherical ZSM-5 zeolite particles with around 2 μm in diameter possess intercrystalline meso-and macropores generated from the aggregation of bar-shape ZSM-5 nanocrystals, which exhibit large specific surface area and mesopore volume. Compared to the ZSM-5 zeolite synthesized by constant temperature hydrothermal method, the hierarchical ZSM-5 zeolites have higher Brønsted acid to Lewis acid ratio (C_BP/C_LP) and strong acid to weak acid ratio (C_s/Cw), as well as the enhanced accessibility of the active sites, which were very important to the catalytic reaction. Catalytic tests reveal that hierarchical ZSM-5-contained catalytic cracking catalyst exhibit an outstanding performance in improving the propylene yield and conversion due to the enhancement of accessibility.
- hierarchical ZSM-5 zeolites,
- two stage varying temperature technique,
- single template,
- spherical structure,
- catalytic cracking performance
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