Citation: CHEN Ping, LIU Shu-Cheng, XU Jiao, QIU Jun-Jie, DAI En-Gao, LIU Yi. Mesoporous Yttria Doped Zirconia Solid Solutions Derived from Bimetallic Y/Zr-UiO-67 and Its Ion Conduction[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 843-849. doi: 10.11862/CJIC.2018.121 shu

Mesoporous Yttria Doped Zirconia Solid Solutions Derived from Bimetallic Y/Zr-UiO-67 and Its Ion Conduction

School of Physical Sciences, Guizhou University, Guiyang 550025, China

Corresponding author: LIU Yi, yliu9@gzu.edu.cn
Received Date: 20 December 2017
Revised Date: 31 January 2018

Figures(9)

Different amounts of Y³⁺ ions have been incorporated into the secondary building units (SBUs) of UiO-67 frameworks during solvothermal crystallization. The SBUs containing integral Zr(Ⅳ)-O and Y(Ⅲ)-O clusters are formed in this bimetallic Y/Zr-UiO-67. Mesoporous yttria doped zirconia is synthesized by two-step calcination treatment using the bimetallic MOFs as a template. This kind of MOFs derived solid solutions has a high BET surface and enhanced oxygen ion conductivity.
- porous materials,
- yttria doped zirconia,
- metal-organic frameworks
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