Citation: YU Ting, GAO Ming-Yan, SONG Yan, LI Dan, LIU Gui-Xia, DONG Xiang-Ting, WANG Jin-Xian. Synthesis, Luminescence and Energy Transfer of Dy³⁺ and Eu³⁺ Co-doped LiGd(MoO₄)₂ Single-Phase Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 857-863. doi: 10.11862/CJIC.2018.116 shu

Synthesis, Luminescence and Energy Transfer of Dy³⁺ and Eu³⁺ Co-doped LiGd(MoO₄)₂ Single-Phase Phosphors

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Key Laboratory of Applied Chemistry and Nanotechnology at Universities of Jilin Province, Changchun 130022, China

Corresponding author: LIU Gui-Xia, liuguixia22@163.com
Received Date: 28 December 2017
Revised Date: 10 February 2018

Figures(10)

Series of Dy³⁺, Eu³⁺ co-doped LiGd(MoO₄)₂ phosphors were prepared via sol-gel method, the samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and fluorescence spectrometer. The results show that the scheelite structured LiGd (MoO₄)₂:Dy³⁺, Eu³⁺ fluorescent powder is irregular and the particle diameter is 1.8 μm. Photoluminescence spectra show that the phosphors exhibit yellow and blue emission of Dy³⁺ and red emission of Eu³⁺ upon 354 nm near ultraviolet light excitation. The critical distance of Dy³⁺ and Eu³⁺ is calculated to be 1.383 nm. The mechanism of energy transfer from Dy³⁺ to Eu³⁺ is dipole-quadrupole interaction. By adjusting the concentration of Dy³⁺ and Eu³⁺, the phosphor can realize the warm-white-light emitting. Moreover, the relationship between the value of correlated color temperature and the rare earth ions (Dy³⁺, Eu³⁺) doped concentration was studied in detail.
- sol-gel method,
- phosphor,
- warm-white-light emitting,
- energy transfer
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Synthesis, Luminescence and Energy Transfer of Dy3+ and Eu3+ Co-doped LiGd(MoO4)2 Single-Phase Phosphors

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Luminescence and Energy Transfer of Dy³⁺ and Eu³⁺ Co-doped LiGd(MoO₄)₂ Single-Phase Phosphors