Citation: WU Hao, WANG Yuan, ZHANG Ling, KANG Rui-Fang, WU Wei-Na. Synthesis, Crystal Structure and DNA-Binding Property of Ag(Ⅰ) Complex with 1-(3-Ethylpyrazin-2-yl)ethylidene-4-phenylsemicarbazide[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1137-1142. doi: 10.11862/CJIC.2018.108 shu

Synthesis, Crystal Structure and DNA-Binding Property of Ag(Ⅰ) Complex with 1-(3-Ethylpyrazin-2-yl)ethylidene-4-phenylsemicarbazide

Henan Key Laboratory of Coal Green Conversion, College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: WANG Yuan, wangyuan08@hpu.edu.cn WU Wei-Na, wuwn08@hpu.edu.cn
Received Date: 5 December 2017
Revised Date: 18 January 2018

Figures(3)

The title complex[Ag₂(HL)(NO₃)₂]_n (1) (HL=1-(3-ethylpyrazin-2-yl)ethylidene-4-phenylsemicarbazide) has been synthesized and characterized by single crystal X-ray diffraction, elemental analysis and IR spectroscopy.X-ray diffraction analysis results show that in 1, HL acts as a neutral tetradentate ligand to connect with two Ag(Ⅰ) centers, one of which adopts a distorted square pyramid coordination geometry involving one HL ligand with ON₂ donor set (carbonyl O, imine N, and pyrazine N1 atoms) and two monodentate nitrate anions; while the other one is four-coordinated with one monodentate nitrate anion, one bidentate nitrate anion and pyrazine N4 atom, thus giving a planar square coordination geometry.Adjacent Ag(Ⅰ) ions are further connected by bridged nitrate anions to form a 2D framework; Moreover, the fluorescence spectra indicate that the interaction of the complex 1 with DNA is stronger than that of the ligand HL.
- semicarbazone,
- Ag(Ⅰ)complex,
- pyrazine,
- DNA interaction
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