Citation: WANG Li-Wen, SHANG Qi-Gao, ZHOU Jing-Jing, ZHOU Hong, PAN Zhi-Quan, CHENG Qing-Rong. Crystal Structures and Properties of Two Linear Trinuclear Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 957-966. doi: 10.11862/CJIC.2018.105 shu

Crystal Structures and Properties of Two Linear Trinuclear Complexes

Wuhan Institute of Technology, Wuhan 430074, China

Corresponding author: CHENG Qing-Rong, chengqr383121@sina.com
Received Date: 29 September 2017
Revised Date: 4 February 2018

Figures(11)

Two new trinuclear complexes, [Co₂^ⅢCo^ⅡL₂(μ-OAc)₄] (1) and[Ni₃L₂(μ-OAc)₂(CH₃OH)₂]·2H₂O (2), were obtained and fully characterized, where L was the condensation product between 2-hydroxy-1, 3-propane diamine and 5-fluorosalicylaldehyde. The interaction of complex 1 with DNA has been investigated by spectroscopy, viscosity measurements and electrochemical studies. Absorption spectroscopic investigation reveals intercalative binding of Co complex with DNA, with a binding constant of 2.43×10⁵ L·mol^-1. Fluorescence spectroscopy shows that complex 1 can displace ethidium bromide and bind to DNA, with a quenching constant of 4.92×10³ L·mol^-1. The variable-temperature magnetisms of complexes 1 and 2 show that there are antiferromagnetic couplings among the three metal centers in both complexes. CCDC: 1587441, 1; 1587442, 2.
- linear trinuclear complex,
- crystal structure,
- DNA cleavage activity,
- magnetism
1. [1]
  Tangoulis V, Raptopoulou C P, Paschalidou S, et al. Angew. Chem., Int. Ed., 1997, 36:1083-1085 doi: 10.1002/(ISSN)1521-3773
2. [2]
  Mukherjee A, Nethaji M, Chakravarty A R. Angew. Chem., Int. Ed., 2004, 43:87-90 doi: 10.1002/(ISSN)1521-3773
3. [3]
  Nishida Y, Kida S. J. Chem. Soc. Dalton Trans., 1986, 12:2633-2640
4. [4]
  Hilms E, Elias H, Paulus H. J. Chem, Soc. Dalton Trans., 1986, 10:2169-2172
5. [5]
  Breslow R, Zhang X J, Xu R, et al. J. Am. Chem. Soc., 1996, 118:11678-11679 doi: 10.1021/ja962295f
6. [6]
  Adam W, Fell R T, Stegmann V R, et al. J. Am. Chem. Soc., 1998, 120:708-714 doi: 10.1021/ja9726668
7. [7]
  Routier S, Bernier J L, Waring M J, et al. J. Org. Chem., 1996, 61:2326-2331 doi: 10.1021/jo951840c
8. [8]
  Lamour E, Routier S, Bernier J L, et al. J. Am. Chem. Soc., 1999, 121:1862-1869 doi: 10.1021/ja982221z
9. [9]
  Maleev V I, North M, Larionov V A, et al. Adv. Synth. Catal., 2014, 356:1803-1810 doi: 10.1002/adsc.201400091
10. [10]
  Kunkely H, Vogle A. J. Photochem. Photobiol. A:Chem., 2001, 138:51-54 doi: 10.1016/S1010-6030(00)00381-6
11. [11]
  Honda T, Kojima T, Fukuzumi S. J. Am. Chem. Soc., 2012, 134:4196-4206 doi: 10.1021/ja209978q
12. [12]
  Salehi M, Amirnasr M, Meghdadi S, et al. Polyhedron, 2014, 81:90-97 doi: 10.1016/j.poly.2014.05.049
13. [13]
  Aduldecha S, Hathaway B. J. Chem. Soc. Dalton Trans., 1991, 4:993-998
14. [14]
  Chien C H, Chang J C, Yeh C Y, et al. Dalton Trans., 2006, 17:2106-2113
15. [15]
  Cotton F A, Murillo C A, Wang Q S. Inorg. Chem. Commun., 2007, 10:1088-1090 doi: 10.1016/j.inoche.2007.06.001
16. [16]
  Cheng Q R, Zhang F Q, Zhou H, et al. J. Coord. Chem., 2015, 68(11):1997-2005 doi: 10.1080/00958972.2015.1032272
17. [17]
  Cheng Q R, Yu L, Li P, et al. Transition Met. Chem., 2015, 40:789-797 doi: 10.1007/s11243-015-9973-7
18. [18]
  Cheng Q R, You D, Hu H, et al. J. Coord. Chem., 2014, 67(5):910-920 doi: 10.1080/00958972.2014.905685
19. [19]
  Cheng Q R, Li P, Zhou H, et al. J. Coord. Chem., 2014, 67(9):1584-1595 doi: 10.1080/00958972.2014.924623
20. [20]
  Cheng Q R, Zhou H, Pan Z Q. J. Mol. Struct., 2014, 1071:255-262
21. [21]
  Cheng Q R, Zhou H, Pan Z Q. Polyhedron, 2014, 81:668-674 doi: 10.1016/j.poly.2014.07.022
22. [22]
  CHENG Qing-Rong, ZHANG Ya, ZHOU Hong, et al. Chinese J. Inorg. Chem., 2014, 33(11):2591-2500
23. [23]
  Cheng Q R, Zhou H, Pan Z Q. Transition Met. Chem., 2012, 37:407-414 doi: 10.1007/s11243-012-9602-7
24. [24]
  SMART and SAINT, Area Detector Control and Integration Software, Siemens Analytical X-ray Systems Inc, Madison, WI, 1996.
25. [25]
  Sheldrick G M. SHELXTL Version 5.1, Software Reference Manual, Bruker AXS Inc., Madison, WI, 1997.
26. [26]
  Neves A, Brito M A de, Vencato I, et al. Inorg. Chem., 1996, 35:2360-2368 doi: 10.1021/ic950456v
27. [27]
  Gaber B P, Miskowski V, Spiro T G. J. Am. Chem. Soc., 1974, 96:6868-6873 doi: 10.1021/ja00829a010
28. [28]
  Tian J L, Feng L, Gu W, et al. J. Inorg. Biochem., 2007, 101:196-202 doi: 10.1016/j.jinorgbio.2006.08.009
29. [29]
  Wolfe A, Shimer G H, Meehan T. Biochemistry, 1987, 26:6392-6396 doi: 10.1021/bi00394a013
30. [30]
  Meyer-Almes F J, Porschke D. Biochemistry, 1993, 32:4246-4253 doi: 10.1021/bi00067a012
31. [31]
  Qian J, Gu W, Liu H, et al. Dalton Trans., 2007:1060-1066
32. [32]
  Zhang J A, Pan M, Yang R, et al. Polyhedron, 2010, 29:590-591
33. [33]
  Ibrahim M S. Anal. Chim. Acta, 2001, 443:65-71
34. [34]
  Michael T C, Marisol R, Alle J B. J. Am. Chem. Soc., 1989, 111(24):8901-8911 doi: 10.1021/ja00206a020
35. [35]
  Satyanarayana S, Dabrowiak J C, Chaires J B. Biochemistry, 1993, 32:2573-2584 doi: 10.1021/bi00061a015
36. [36]
  Sun J, Shuo S, An Y, et al. Polyhedron, 2008, 27:2845-2850 doi: 10.1016/j.poly.2008.06.009
37. [37]
  Liu J G, Ye B H, Li H, et al. J. Inorg. Biochem., 1999, 76:265-271 doi: 10.1016/S0162-0134(99)00154-3
38. [38]
  Ding B, Yang E C, Zhao X J, et al. J. Coord. Chem., 2008, 23(61):3793-3799
39. [39]
  Clérac R, Cotton F A, Dunbar K R, et al. Inorg. Chem., 1999, 38:2655-2657 doi: 10.1021/ic990006t
1. [1]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
2. [2]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
3. [3]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
4. [4]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
5. [5]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
6. [6]
  Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
9. [9]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
10. [10]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
11. [11]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
12. [12]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
13. [13]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
14. [14]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
15. [15]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
16. [16]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
17. [17]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
18. [18]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
19. [19]
  Jingwen Zhao , Jianpu Tang , Zhen Cui , Limin Liu , Dayong Yang , Chi Yao . A DNA micro-complex containing polyaptamer for exosome separation and wound healing. Chinese Chemical Letters, 2024, 35(9): 109303-. doi: 10.1016/j.cclet.2023.109303
20. [20]
  Chang Liu , Tao Wu , Lijiao Deng , Xuzi Li , Xin Fu , Shuzhen Liao , Wenjie Ma , Guoqiang Zou , Hai Yang . Programmed DNA walkers for biosensors. Chinese Chemical Letters, 2024, 35(9): 109307-. doi: 10.1016/j.cclet.2023.109307

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(326)
HTML views(52)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142