Citation: WANG Hong-Sheng, LI Gong-Chun, WU Yan-Chao, ZHANG Wan-Qiang, CHENG Xin-Hua. Structures and Luminescent Properties of Three Heterotrimetallic Ln(Ⅲ)-Sr(Ⅱ)-K(Ⅰ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 655-661. doi: 10.11862/CJIC.2018.103 shu

Structures and Luminescent Properties of Three Heterotrimetallic Ln(Ⅲ)-Sr(Ⅱ)-K(Ⅰ) Complexes

1.
School of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan 461000, China
2.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), Nankai University, Tianjin 300071, China

Corresponding author: WANG Hong-Sheng, xcuwaller@163.com
Received Date: 11 August 2017
Revised Date: 29 January 2018

Figures(9)

Three coordination polymers with the molecular formula[LnSrK(ptc)₂(H₂O)]_n (Ln=Sm (1), Dy (2), Gd (3), H₃ptc=2, 4, 6-pyridinetricarboxylic acid) were synthesized by hydrothermal reaction of the solutions of Ln(ClO₄)₃, SrCO₃, K₂CO₃ and H₃ptc at 180℃. The structures of three complexes were determined by X-ray single crystal diffraction and the results showed they are isomorphic compounds and crystallize in triclinic system, P1 space group. The ptc ligands bonded with three metal ions Ln (Sm (1), Dy (2) and Gd (3)), Sr, K with two types of coor-dination modes:connecting seven metal ions and connecting eight metal ions. Ln(Ⅲ) is eight-coordinated by six oxygen atoms from carboxyl groups and two nitrogen atoms from two pyridyl rings. Sr(Ⅱ) ion is also eight-coordinated but the coordination atoms are all oxygen atoms. K(Ⅰ) is coordinated by five oxygen atoms. The emission spectra show Sm(Ⅲ)-Sr(Ⅱ)-K(Ⅰ) and Dy(Ⅲ)-Sr(Ⅱ)-K(Ⅰ) complexes both emit the characteristic fluorescence of Sm(Ⅲ) and Dy(Ⅲ). The Gd(Ⅲ)-Sr(Ⅱ)-K(Ⅰ) complex emits green fluorescence but it is resulted from the charge transfer transitions between the ligands and Gd(Ⅲ).
- 2, 4, 6-pyridinetricarboxylic acid,
- rare earth,
- strontium,
- potassium,
- coordination polymer
1. [1]
  Liu Q Y, Wang W F, Wang Y L, et al. Inorg. Chem., 2012, 51:2381-2392 doi: 10.1021/ic2023727
2. [2]
  QUAN Jing-Miao, LEI Hai-Rui, LIU Feng -Yi, et al. Scientia Sinica Chimica, 2017, 47(7):876-881
3. [3]
  Cui Y J, Xu H, Yue Y F, et al. J. Am. Chem. Soc., 2012, 134:3979-3982 doi: 10.1021/ja2108036
4. [4]
  ZHAO Peng-Fei, SHE Jiang-Bo, LI Dong-Dong, et al. Acta Photonica Sinica, 2014, 43(2):0216001
5. [5]
  ZHOU Liang, DENG Rui-Ping, ZHANG Hong-Jie. Chinese J. Inorg. Chem., 2014, 30(1):113-120
6. [6]
  Zhao B, Cheng P, Dai Y, et al. Angew. Chem. Int. Ed., 2003, 42:934-936 doi: 10.1002/anie.200390248
7. [7]
  Zhao B, Cheng P, Chen X Y, et al. J. Am. Chem. Soc., 2004, 126:3012-3013 doi: 10.1021/ja038784e
8. [8]
  Zhao X Q, Zhao B, Ma Y, et al. Inorg. Chem., 2007, 46:5832-5834 doi: 10.1021/ic7007446
9. [9]
  Gao H L, Zhao B, Zhao X, et al. Inorg. Chem., 2008, 47:11057-11061 doi: 10.1021/ic801332a
10. [10]
  Cui Y J, Yue Y F, Qian G D, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
11. [11]
  Huang Y G, Jiang F L, Hong M C. Coord. Chem. Rev., 2009, 253:2814-2834 doi: 10.1016/j.ccr.2009.05.007
12. [12]
  Mishra S, Ledoux G, Jeanneau E, et al. Dalton Trans., 2012, 41:1490-1502 doi: 10.1039/C1DT11070E
13. [13]
  Zhao X Q, Zuo Y, Gao D L, et al. Cryst. Growth Des., 2009, 9:3948-3957 doi: 10.1021/cg9000818
14. [14]
  Gao H L, Yi L, Ding B, et al. Inorg. Chem., 2006, 45:481-483 doi: 10.1021/ic051707v
15. [15]
  Kou H Z, Zhou B C, Gao S, et al. Angew. Chem. Int. Ed., 2003, 42:3288-3291 doi: 10.1002/anie.200351248
16. [16]
  Kou H Z, Zhou B C, Wang R J. Inorg. Chem., 2003, 42:7658-7665 doi: 10.1021/ic0348502
17. [17]
  Zhang W Z, Lv T Y, Wei D Z, et al. Inorg. Chem. Commun., 2011, 14:1245-1249 doi: 10.1016/j.inoche.2011.04.032
18. [18]
  Wang H S, Xia J, Zhai B, et al. J. Coord. Chem., 2014, 67:3234-3242 doi: 10.1080/00958972.2014.964226
19. [19]
  Syper L, Kloc K, Mlochowski J. Tetrahedron, 1980, 36:123-129 doi: 10.1016/0040-4020(80)85034-4
20. [20]
  Sheldrick G M. SHELXS 97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
21. [21]
  Sheldrick G M. SHELXL 97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
1. [1]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
2. [2]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
3. [3]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
4. [4]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
5. [5]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
6. [6]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
7. [7]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
8. [8]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
9. [9]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
10. [10]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
11. [11]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
12. [12]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
13. [13]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
14. [14]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
15. [15]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
16. [16]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
17. [17]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
18. [18]
  Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, 2024, 39(10): 255-260. doi: 10.12461/PKU.DXHX202404105
19. [19]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
20. [20]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(508)
HTML views(81)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142