Citation: ZHENG Yun-Yun, HUANG Rui-Min, WEI Hang, HUANG Biao, SU De-Sen, FU Jian-Wei. Syntheses, Characterization and Crystal Structures of Ln(Ⅲ) Complexes Based on 2, 5-Thiophenedicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 733-738. doi: 10.11862/CJIC.2018.102 shu

Syntheses, Characterization and Crystal Structures of Ln(Ⅲ) Complexes Based on 2, 5-Thiophenedicarboxylic Acid

1.
Institute of Quality Standards and Testing Technology Research of Agro-products, Fujian Academy of Agricultural Sciences, Fuzhou 350003, China
2.
Institute of Subtropical Agricultural Research, Fujian Academy of Agricultural Sciences, Zhangzhou, Fujian 3630005, China

Corresponding author: FU Jian-Wei, fjw9238@163.com
Received Date: 4 August 2017
Revised Date: 28 February 2018

Figures(4)

Three lanthanide-based coordination polymers, namely {[La(OH)(SO₄)]}_n (1), {[La₂(TDC)₂(SUC)]}_n (2) and {[Gd₂(TDC)₂(ox)(H₂O)₄]·2H₂O}_n (3) (H₂TDC=2, 5-thiophenedi-carboxylic acid, SUC=succinate, ox=oxalate), were synthesized through hydrothermal reaction of H₂TDC and Ln(NO₃)₃ (Ln=La, Gd). Investigation on the crystal structure indicates that complex 2 and 3 feature 3D frameworks. Crystal data are orthorhombic, space group Pbca, a=1.372 8(4) nm, b=0.704 0(2) nm, c=2.136 2(6) nm, Z=8 for 2; and monoclinic, space group, C2/c, a=1.934 3(4) nm, b=0.990 5(2) nm, c=1.252 8(3) nm, β=107.463(4)°, Z=4 for 3.
- thiophenedicarboxylate,
- lanthanide,
- crystal,
- synthesis
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