Citation: TAN De-Xin, WANG Yan-Li. Pd-Ag Alloy Nanowires: Facile Visible-Light-Assisted Synthesis and Electrocatalytic Activity toward Ethanol Oxidation[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 777-783. doi: 10.11862/CJIC.2018.098 shu

Pd-Ag Alloy Nanowires: Facile Visible-Light-Assisted Synthesis and Electrocatalytic Activity toward Ethanol Oxidation

TAN De-Xin ^, ,
WANG Yan-Li ^,

School of Chemistry and Chemical Engineering, Lingnan Normal University, Zhanjiang, Guangdong 524048, China

Corresponding author: TAN De-Xin, tdxin@163.com WANG Yan-Li, ylwang1998@163.com
Received Date: 9 November 2017
Revised Date: 22 January 2018

Figures(5)

Using palladium nitrate and silver nitrate as the metal precursor, ethanol and sodium citrate tribasic dehydrate as reducing agents and poly(vinyl pyrrolidone) (PVP) as a stabilizer and guiding agent, Pd-Ag alloy nanowires were synthesized via visible-light-assisted solution approach with a commercial incandescent lamp as light source. The morphologies, crystal structure and optical properties were characterized by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), power X-ray diffraction (PXRD), and UV-visible spectroscopy, respectively. The electrocatalytic properties of the Pd-Ag alloy nanowires modified glassy carbon electrode for ethanol oxidation were investigated by cyclic voltammetry and chronoamperometry. The Pd-Ag alloy nanowires exhibited much better electrocatalytic performance than Pd nanoparticles toward ethanol oxidation reaction in alkaline media in terms of the electrocatalytic activity, anti-poisoning ability and stability.
- Pd-Ag alloy,
- nanowires,
- visible light,
- ethanol,
- electrocatalysis
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