Citation: Mohamad Ali Hikmat, Mahmoud Jamal Azheen, Gerber Thomas, Hosten Eric. Synthesis and Characterization of Complex (BenzMeIm)₂[PtCl₄][J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 728-732. doi: 10.11862/CJIC.2018.096 shu

Synthesis and Characterization of Complex (BenzMeIm)₂[PtCl₄]

1.
Department of Chemistry, College of Education, University of Salahaddin, Erbil, Iraq
2.
Department of Chemistry, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa

Corresponding author: Mohamad Ali Hikmat, hikmatmohamad@yahoo.com
Received Date: 24 August 2017
Revised Date: 25 January 2018

Figures(5)

A complex of (BenzMeIm)₂[PtCl₄] was prepared by the reaction of 1-benzyl-3-methylimidazolium chloride (BenzMeIm-Cl) with PtCl₂. The structure of the complex was characterized by single crystal X-ray analysis, and it crystallizes in the monoclinic P2₁/c space group, with a=0.981 80(5) nm, b=0.861 47(3) nm, c=0.144 332(7) nm, β=92.480(2)°, V=121.96(1) nm³, R₁=0.014 4, wR₂=0.038 8.
- 1-benzyl-3-methylimidazolium chloride,
- Pt(Ⅱ),
- complex,
- crystal structure
1. [1]
  Hassan M, Kozhevnikov I V, Siddiqui H R, et al. Inorg. Chem., 2001, 40:795-800 doi: 10.1021/ic000606o
2. [2]
  Chorbani M H. Acta Crystallogr., Sect. E:Struct. Rep. Online, 2012, E68:o2605
3. [3]
  Herbert J M, Woodgate P D, Denny W A. J. Med. Chem., 1987, 30:2081-2086 doi: 10.1021/jm00394a025
4. [4]
  Lui K C, Chen H H. J. Heterocycl. Chem., 1984, 21:911-912 doi: 10.1002/jhet.v21:3
5. [5]
  Chauvin Y, Olivier H, Wyrvalski C N, et al. J. Catal., 1997, 165:275 doi: 10.1006/jcat.1997.1488
6. [6]
  Appleby D, Hussey C L, Seddon K R, et al. Nature, 1986, 323:614-616 doi: 10.1038/323614a0
7. [7]
  Sun I W, Ward E H, Hussey C L, et al. Inorg. Chem., 1987, 26:2140-2143 doi: 10.1021/ic00260a026
8. [8]
  Schreiter E R, Stevens J E, Ortwerth M F, et al. Inorg. Chem., 1999, 38:3935-3937 doi: 10.1021/ic990062u
9. [9]
  Buttrus N H, Saeed I A, Al-Joburi S A. Raf. J. Sci., 2007, 18:84-90
10. [10]
  APEX 2, SAINT, SADABS, Bruker AXS Inc., Madison, Wisconsin, USA, 1996.
11. [11]
  Sheldrick G M. Acta Crystallogr. Sect. C:Cryst. Struct. Commun., 2015, C71:3-8
12. [12]
  Hübschle C B, Sheldrick G M, Dittrich B. J. Appl. Crystallogr., 2011, 44:1281-1284 doi: 10.1107/S0021889811043202
13. [13]
  Mai K, Takayoshi S. Inorg. Chim. Acta, 2010, 363:3602-3605 doi: 10.1016/j.ica.2010.05.053
14. [14]
  Kriza A, Parnau C, Popa N, et al. J. Inorg. Chem., 2004, 1:179-183
15. [15]
  Venkatesan P, Maruthavanan T. Bull. Chem. Soc. Ethiop., 2011, 25:419-425
16. [16]
  Field L D, Sternhell S, Kalman J R. Organic Structures from Spectra. 3rd Ed. Chichester:John Wiley & Sons, 2005:64
1. [1]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
4. [4]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
9. [9]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
10. [10]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
11. [11]
  Yingying Yan , Wanhe Jia , Rui Cai , Chun Liu . An AIPE-active fluorinated cationic Pt(Ⅱ) complex for efficient detection of picric acid in aqueous media. Chinese Chemical Letters, 2024, 35(5): 108819-. doi: 10.1016/j.cclet.2023.108819
12. [12]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
13. [13]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
14. [14]
  Lian Sun , Honglei Wang , Ming Ma , Tingting Cao , Leilei Zhang , Xingui Zhou . Shape and composition evolution of Pt and Pt₃M nanocrystals under HCl chemical etching. Chinese Chemical Letters, 2024, 35(9): 109188-. doi: 10.1016/j.cclet.2023.109188
15. [15]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
16. [16]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
17. [17]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
18. [18]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
19. [19]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
20. [20]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(611)
HTML views(97)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Characterization of Complex (BenzMeIm)2[PtCl4]

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Characterization of Complex (BenzMeIm)₂[PtCl₄]