Citation: TAN Chao-Pu, HUANG Dian-Hua, LUO Hong-Jun, DU Ke, CAO Yan-Bing, HU Guo-Rong. Effects of Zirconium Substitution on Electrochemical Performance of Li(Ni_0.9Co_0.05Al_0.05)O₂ for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 647-654. doi: 10.11862/CJIC.2018.091 shu

Effects of Zirconium Substitution on Electrochemical Performance of Li(Ni_0.9Co_0.05Al_0.05)O₂ for Lithium-Ion Batteries

1.
School of Metallurgy and Environment, Central South University, Changsha 410083, China
2.
Guangzhou Libode New Materials Co., Ltd., Guangzhou 510800, China

Corresponding author: DU Ke, csutcp@163.com
Received Date: 27 September 2017
Revised Date: 23 January 2018

Figures(7)

Spherical precursor Ni_0.9Co_0.05Al_0.03Zr_0.02(OH)₂ was obtained by controlled crystallization method. A uniform mixture of Ni_0.9Co_0.05Al_0.03Zr_0.02(OH)₂ and LiOH·H₂O was sintered under 750℃ in O₂ atmosphere to synthesize layered Li(Ni_0.9Co_0.05Al_0.03Zr_0.02)O₂ cathode material. SEM images show that the precursor and cathode material have well morphology. XRD patterns show that the product possesse a well-layered α-NaFeO₂ structure. EDXS images show the Zr element in the material is distributed evenly. The cells with the material as cathode display excellent electrochemical performance:an initial discharge capacity of 221.5 mAh·g^-1 at 0.2C between 2.8 and 4.3 V with an initial coulombic efficiency of 90.3%, a discharge capacity of 192.7 mAh·g^-1 at 2C and a capacity retention rate of 92.2% after 100 cycles at 25℃. As the temperature raised to 55℃, the discharge capacity was 236.2 mAh·g^-1 at 0.2C in 2.8~4.3 V, and retained a capacity retention rate of 85.1% after 100 cycles at 2C.
- lithium-ion battery,
- cathode material,
- co-precipitation,
- zirconium substitution
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effects of Zirconium Substitution on Electrochemical Performance of Li(Ni0.9Co0.05Al0.05)O2 for Lithium-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Effects of Zirconium Substitution on Electrochemical Performance of Li(Ni_0.9Co_0.05Al_0.05)O₂ for Lithium-Ion Batteries