Citation: DU Jun-Chen, MA Jiang-Li, WANG Feng-Jun, YANG Dong-Xia, ZHENG Ting-Ting, ZHAO Yun-Kun. Catalytic Oxidation of C₃H₆ and CO over Pt/ZrO₂-Al₂O₃ Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 800-806. doi: 10.11862/CJIC.2018.088 shu

Catalytic Oxidation of C₃H₆ and CO over Pt/ZrO₂-Al₂O₃ Catalyst

1.
State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China
2.
State-Local Joint Engineer Laboratory of Precious Metals Catalytic Technology and Application, Kunming Sino-platinum Metals Catalysts Co., Ltd., Kunming 650106, China
3.
Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China

Corresponding author: YANG Dong-Xia, doris.yang@spmcatalyst.com ZHAO Yun-Kun, yk.zhao@spmcatalyst.com
Received Date: 8 December 2017
Revised Date: 17 January 2017

Figures(5)

The ZrO₂-Al₂O₃ composite oxides with different mass ratio of ZrO₂ to Al₂O₃ were prepared by co-precipitation method. 1.5%Pt/ZrO₂-Al₂O₃ (w/w) serial catalysts were prepared by isovolume impregnation method. The catalytic performance for C₃H₆ and CO oxidation show that Pt/Zr(0.4)-Al catalyst owns the most excellent catalytic activity. The temperature of light-off (T₅₀) and the complete conversion temperature (T₉₀) were less than 125 and 150℃ respectively. The effects of catalyst phase structure, specific surface area and particle size on the catalytic activity were investigated by XRD, N₂ adsorption-desorption, H₂-TPR and CO pulse adsorption. It is found that ZrO₂-Al₂O₃ composite oxides have the mesoporous texture, large specific surface area, and a new phase of Al_xZr_1-xO_y solid solution was also produced. The mass ratio of ZrO₂ to Al₂O₃ is the key to improving the interaction between Pt and ZrO₂-Al₂O₃, promoting the dispersion of Pt and enhancing the low temperature oxidation activity of Pt/ZrO₂-Al₂O₃ catalyst.
- HC&CO oxidation,
- platinum based catalyst,
- ZrO₂-Al₂O₃,
- size effect,
- exhaust purification
1. [1]
  Morgan C. Johnson Matthey Technol. Rev., 2014, 58(4):217-220 doi: 10.1595/205651314X684726
2. [2]
  Heck R M, Farrauto R J, Weidenkaff A. Appl. Catal., A, 2001, 221(1):443-457
3. [3]
  Gandhi H S, Graham G W, Mccabe R W. J. Catal., 2003, 216(1):433-442
4. [4]
  KANG Xin-Ting, TANG Hui-Ping, ZHANG Jian, et al. Rare Metal Materials and Engineering, 2006, 35(Suppl.2):442-447
5. [5]
  Keav S, Matam S K, Ferri D, et al. Catalysts, 2014, 4(3):226-255 doi: 10.3390/catal4030226
6. [6]
  Wang J H, Chen H, Hu Z C, et al. Catal. Rev. Sci. Eng., 2015, 57(1):79-144 doi: 10.1080/01614940.2014.977059
7. [7]
  Bagwan N, Satpute S. International Journal of Advanced Production and Industrial Engineering, 2017, 504:22-26
8. [8]
  SONG Wei-Cong, SHI Zhong-Hua, YAO Yan-Lin, et al. Chinese J. Inorg. Chem., 2009, 25(5):838-843
9. [9]
  Yang C W, Zhang Q, Li J, et al. J. Energy Chem., 2016, 25(3):375-380 doi: 10.1016/j.jechem.2016.01.011
10. [10]
  He J J, Wang C X, Zheng T T, et al. Johnson Matthey Technol. Rev., 2016, 60(3):196-203 doi: 10.1595/205651316X691960
11. [11]
  DU Jun-Chen, CHANG Shi-Ying, HUANG Wei-Qiang, et al. Journal of Molecular Catalysis (China), 2015, 29(5):482-493
12. [12]
  Shen M Q, Song L Y, Wang J, et al. Catal. Commun., 2012, 22(18):28-33
13. [13]
  Zheng T T, He J J, Xia W Z, et al. Catal. Commun., 2015, 71:51-55 doi: 10.1016/j.catcom.2015.08.012
14. [14]
  LI Ning, LUO Lai-Tao. Chin. J. Catal., 2007, 28(9):773-778
15. [15]
  Dömök M, Oszkó A, Baán K, et al. Appl. Catal., A, 2010, 383(1):33-42
16. [16]
  Souza M M V M, Aranda D A G, Schmal M. J. Catal., 2001, 204(2):498-511 doi: 10.1006/jcat.2001.3398
17. [17]
  Morán-Pineda M, Castillo S, López T, et al. Appl. Catal., B, 1999, 21(2):79-88 doi: 10.1016/S0926-3373(99)00010-7
18. [18]
  Long E Y, Wang Y, Zhang X Y, et al. Chin. J. Catal., 2010, 31(3):313-316
19. [19]
  Wang Y, Tang S Y, Long E, et al. Chin. J. Catal., 2011, 32(2):303-308
20. [20]
  Cooper J, Beecham J. Platinum Met. Rev., 2013, 57(4):281-288 doi: 10.1595/147106713X671457
21. [21]
  Matsouka V, Konsolakis M, Yentekakis I V, et al. Top. Catal., 2011, 54(16/17/18):1124-1134
22. [22]
  Shi Z H, Gong M C, Chen Y Q. Chin. Chem. Lett., 2006, 17(9):1271-1274
23. [23]
  Wang G, Meng M, Zha Y Q, et al. Fuel, 2010, 89(9):2244-2251 doi: 10.1016/j.fuel.2010.03.031
24. [24]
  Fang R M, Cui Y J, Chen S J, et al. Chin. J. Catal., 2015, 36(2):229-236 doi: 10.1016/S1872-2067(14)60214-X
25. [25]
  Yang X, Yang L Y, Lin S Y, et al. Chin. J. Catal., 2014, 35(8):1267-1280 doi: 10.1016/S1872-2067(14)60157-1
26. [26]
  Zhu Z Z, Lu G Z, Guo Y, et al. J. Ind. Eng. Chem., 2012, 18(6):2135-2140 doi: 10.1016/j.jiec.2012.06.008
27. [27]
  DU Jun-Chen, ZHANG Ai-Min, MA Jiang-Li, et al. Chinese J. Inorg. Chem., 2017, 33(3):415-420 doi: 10.11862/CJIC.2017.027
28. [28]
  Wang Y, Xu H D, Shang H Y, et al. J. Energy Chem., 2014, 23:461-467 doi: 10.1016/S2095-4956(14)60172-8
29. [29]
  Zhao Y J, Zhou J, Zhang J G, et al. J. Mol. Catal. A:Chem., 2009, 309(1):35-39
30. [30]
  Sing K S W. Pure Appl. Chem., 1985, 57(4):603-619 doi: 10.1351/pac198557040603
31. [31]
  XU Hui-Yuan, LUO Jing-Jie, YAN Chun-Rong, et al. Journal of Fuel Chemistry and Techno-logy, 2012, 40(11):1370-1402
32. [32]
  YAN Qian-Gu, GAO Li-Zhen, YUAN Song -Yue, et al. Chem. J. Chinese Universities, 1998, 19(8):1300-1303
33. [33]
  Bourane A, Olivier Dulaurent A, Bianchi D. Langmuir, 2001, 17(18):5496-5502 doi: 10.1021/la0015361
34. [34]
  Fanson P T, Delgass W N, Lauterbach J. J. Catal., 2001, 204(1):35-52 doi: 10.1006/jcat.2001.3369
35. [35]
  Avila M S, Vignatti C I, Apesteguía C R, et al. Catal. Lett., 2010, 134(1/2):118-123
1. [1]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
2. [2]
  Chaochao Wei , Ru Wang , Zhongkai Wu , Qiyue Luo , Ziling Jiang , Liang Ming , Jie Yang , Liping Wang , Chuang Yu . Revealing the size effect of FeS₂ on solid-state battery performances at different operating temperatures. Chinese Chemical Letters, 2024, 35(6): 108717-. doi: 10.1016/j.cclet.2023.108717
3. [3]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
4. [4]
  Ting-Ting Huang , Jin-Fa Chen , Juan Liu , Tai-Bao Wei , Hong Yao , Bingbing Shi , Qi Lin . A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect. Chinese Chemical Letters, 2024, 35(7): 109281-. doi: 10.1016/j.cclet.2023.109281
5. [5]
  Bingbing Shi , Yuchun Wang , Yi Zhou , Xing-Xing Zhao , Yizhou Li , Nuoqian Yan , Wen-Juan Qu , Qi Lin , Tai-Bao Wei . A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions. Chinese Chemical Letters, 2024, 35(10): 109540-. doi: 10.1016/j.cclet.2024.109540
6. [6]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
7. [7]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
8. [8]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
9. [9]
  Ying Zhao , Yin-Hang Chai , Tian Chen , Jie Zheng , Ting-Ting Li , Francisco Aznarez , Li-Long Dang , Lu-Fang Ma . Size-controlled synthesis and near-infrared photothermal response of Cp* Rh-based metalla[2]catenanes and rectangular metallamacrocycles. Chinese Chemical Letters, 2024, 35(6): 109298-. doi: 10.1016/j.cclet.2023.109298
10. [10]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
11. [11]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
12. [12]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
13. [13]
  Jaeyong Ahn , Zhenping Li , Zhiwei Wang , Ke Gao , Huagui Zhuo , Wanuk Choi , Gang Chang , Xiaobo Shang , Joon Hak Oh . Surface doping effect on the optoelectronic performance of 2D organic crystals based on cyano-substituted perylene diimides. Chinese Chemical Letters, 2024, 35(9): 109777-. doi: 10.1016/j.cclet.2024.109777
14. [14]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
15. [15]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
16. [16]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
17. [17]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
18. [18]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
19. [19]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
20. [20]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(658)
HTML views(128)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic Oxidation of C3H6 and CO over Pt/ZrO2-Al2O3 Catalyst

Metrics

通讯作者: 陈斌, bchen63@163.com

Catalytic Oxidation of C₃H₆ and CO over Pt/ZrO₂-Al₂O₃ Catalyst