Citation: LU Si-Yu, LIU Xu-Ri, BI Guan, WANG Yao-Kai, TIAN Hao-Tian, SUN Jing. Preparation and Properties of Temperature Sensitive Paint Based on Eu(DBM)₃ Bipy as Fluorescence Probe[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 683-688. doi: 10.11862/CJIC.2018.083 shu

Preparation and Properties of Temperature Sensitive Paint Based on Eu(DBM)₃ Bipy as Fluorescence Probe

LU Si-Yu ¹ ,
LIU Xu-Ri ^1,2 ,
BI Guan ¹ ,
WANG Yao-Kai ¹ ,
TIAN Hao-Tian ¹ ,
SUN Jing ^1,,

1.
College of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China
2.
College of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China

Corresponding author: SUN Jing, sj-cust@126.com
Received Date: 10 November 2017
Revised Date: 26 December 2017

Figures(5)

Probe Eu(DBM)₃ Bipy was prepared by europium oxide (Eu₂O₃), dibenzoylmethane (DBM) and 2-2'-dipyridyl(Bipy). The temperature sensitive paint (TSP) was compounded by the polymerization of the probe molecule, methyl methacrylate (MMA) and the initiator of benzoyl peroxide (BPO). The structure, morphology, luminescence property of probe molecule and the temperature quenching property of the temperature sensitive paint (TSP) was characterized by infrared spectrometer, UV-Vis spectrometer, scanning electron microscopy and fluorescence spectrometer. The results of infrared and UV absorption spectrum analysis showed that the rare earth ion Eu³⁺ coordinates to ligands and Eu(DBM)₃ Bipy probe molecule was successfully synthesized. Scanning electron microscopy spectrum and energy spectrum analysis showed that Eu(DBM)₃ Bipy probe molecule is fragmented, and the size is about 150 nm, which is mainly composed of four elements, C, N, O and Eu. The fluorescence spectra showed that the optimum emission wavelength is 612 nm under 367 nm excitation, and Bipy as second ligand has a gain effect on Eu(DBM)₃. Temperature sensitive paint fluorescence emission characteristics test under different temperature conditions, found that the temperature sensitive paint Eu(DBM)₃ Bipy/PMMA has good characteristics of fluorescence quenching of temperature in 40~90℃, and the temperature range of the highest temperature sensitivity at 40~60℃.
- temperature sensitive paint,
- probe molecule,
- temperature quenching
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Preparation and Properties of Temperature Sensitive Paint Based on Eu(DBM)3 Bipy as Fluorescence Probe

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通讯作者: 陈斌, bchen63@163.com

Preparation and Properties of Temperature Sensitive Paint Based on Eu(DBM)₃ Bipy as Fluorescence Probe