Citation: LI Hui-Jun, HE Ya-Ling, ZHANG Ning, LI Qing-Qing, XU Zhou-Qing, WANG Yuan. Structural Differences of Two MOFs Adjusted by Central Metal Ions Inducing Different Photodegradation Efficiencies[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 560-568. doi: 10.11862/CJIC.2018.078 shu

Structural Differences of Two MOFs Adjusted by Central Metal Ions Inducing Different Photodegradation Efficiencies

College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: XU Zhou-Qing, zhqxu@hpu.edu.cn WANG Yuan, wangyuan08@hpu.edu.cn
Received Date: 22 September 2017
Revised Date: 14 December 2017

Figures(8)

By Reactions of Cu(Ⅱ), Co(Ⅱ) with H₂PPCA ligand (H₂PPCA=5-pyrazin-2-yl-1H-pyrazole-3-carboxylic acid) in the same hydrothermal conditions resulted in two distinct structural metal-organic frameworks (MOFs), namely, [Cu(PPCA)(H₂O)]·H₂O (HPU-7) and {[Co(PPCA)(H₂O)]·H₂O}_n (HPU-8). HPU-7 that obtained from CuCl₂·2H₂O at 160℃ is a dinuclear cluster based on Cu(Ⅱ) ions and PPCA^2- ligands. HPU-8 synthesized by Co(NO₃)₂·6H₂O at 160℃ exhibits a 4, 4-connected 2D layer connected by dinuclear Co(Ⅱ) clusters and the skeletons of the PPCA^2- ligands. The structural differences are dependent on the coordination geometries of central metal ions. And due to the structural differences, the two complexes display different photodegradation efficiencies toward methylene blue (MB).
- dinuclear cluster,
- 2D layer,
- structural differences,
- photodegradation efficiency
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