Citation: ZHANG Yang, WANG Jian. Construction of Two Coordination Polymers Based on 5-Methoxyisophthalic Acid Ligand: Structures, Luminescence and Catalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 589-596. doi: 10.11862/CJIC.2018.073 shu

Construction of Two Coordination Polymers Based on 5-Methoxyisophthalic Acid Ligand: Structures, Luminescence and Catalytic Properties

ZHANG Yang ^, ,
WANG Jian

College of Chemical Engineering, Guangdong University of Petrochemical Technology, Maoming, Guangdong 525000, China

Corresponding author: ZHANG Yang, yangzhang79@126.com
Received Date: 11 October 2017
Revised Date: 20 November 2017

Figures(8)

Two new 1D cadmium/cobalt-based coordination polymers, {[Cd₂(CH₃O-ip)₂(ethanol)₂(H₂O)₄]·3H₂O}_n (1) and {[Co₂(CH₃O-ip)₂(dmbpy)(H₂O)₄]·H₂O·C₂H₃N}_n (2) (CH₃O-H₂ip=5-methoxyisophthalic acid, dmbpy=2, 2'-dimethyl -4, 4'-bipyridine, C₂H₃N=acetonitrile), were synthesized in mixed solvent and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis (TGA), powder X-ray diffraction and single-crystal X-ray diffraction. Both complexes are synthesized using dual linkers (CH₃O-H₂ip and dmbpy). Complex 1 is a wave-like chain and further connected into 2D network through O-H…O hydrogen bonds, whereas 2 shows a ladder chain and further linked into 3D supramolecular framework by O-H…O, O-H…N and C-H…O hydrogen bonds. Furthermore, the luminescence property of 1 and the catalytic degradation of methyl orange in a Fenton-like process of 1~2 are also investigated.
- coordination polymers,
- transition metals,
- crystal structure,
- hydrogen bonds,
- luminescent property,
- catalytic property
1. [1]
  Yang X, Xu Q. Cryst. Growth Des., 2017, 17:1450-1455 doi: 10.1021/acs.cgd.7b00166
2. [2]
  Li J, Fu H R, Zhang J, et al. Inorg. Chem., 2015, 54:3093-3095 doi: 10.1021/acs.inorgchem.5b00316
3. [3]
  Gu Z G, Li D J, Zheng C, et al. Angew. Chem. Int. Ed., 2017, 56:6853-6858 doi: 10.1002/anie.201702162
4. [4]
  Ding L G, Yao B J, Jiang W L, et al. Inorg. Chem., 2017, 56: 2337-2344 doi: 10.1021/acs.inorgchem.6b03169
5. [5]
  Wu Y, Li B H, Liu J Q, et al. Inorg. Chem. Commun., 2017, 82:24-26 doi: 10.1016/j.inoche.2017.05.003
6. [6]
  Xiong C Y, Wang H J, Liang W B, et al. Chem. Eur. J., 2015, 21:9825-9832 doi: 10.1002/chem.201500909
7. [7]
  XIAO Bo-An, CHEN Shui-Sheng. Chinese J. Inorg. Chem., 2017, 33(2):347-353 doi: 10.11862/CJIC.2017.014
8. [8]
  Ma D Y, Li Z, Xiao J X, et al. Inorg. Chem., 2015, 54:6719-6726 doi: 10.1021/acs.inorgchem.5b00335
9. [9]
  Zhang X, Wang W, Hu Z, et al. Coord. Chem. Rev., 2015, 284:2O6-235 doi: 10.1016/j.ccr.2014.10.006
10. [10]
  Guo H, Zheng Z, Zhang Y, et al. Sens. Actuators B, 2017, 248:430-436 doi: 10.1016/j.snb.2017.03.147
11. [11]
  Rao A S, Pal A, Ghosh R, et al. Inorg. Chem., 2009, 48:1802-1804 doi: 10.1021/ic802171b
12. [12]
  Liu L, Huang S P, Yang G D, et al. Cryst. Growth Des., 2010, 10:930-936 doi: 10.1021/cg901259e
13. [13]
  LIU Zhi-Qiang, HUANG Yong-Qing, SUN Wei-Yin, et al. Chinese J. Inorg. Chem., 2017, 33(11):1959-1969 doi: 10.11862/CJIC.2017.244
14. [14]
  Li C P, Du M. Chem. Commun., 2011, 47:5958-5972 doi: 10.1039/c1cc10935a
15. [15]
  Singh M K, Banerjee A. Cryst. Growth Des., 2013, 13:2413-2425 doi: 10.1021/cg4005196
16. [16]
  Zlatogorsky S, Ingleson M J. Dalton Trans., 2012, 41:2685-2693 doi: 10.1039/c2dt12048h
17. [17]
  APEX Ⅱ Software, Ver. 6.3.1, Bruker AXS Inc, Madison, Wisconsin, USA, 2004.
18. [18]
  Sheldrick G M. Acta Crystallogr. Sect. A: Found. Crystallogr., 2008, A64:112-122
19. [19]
  Devi L G, Kumar S G, Reddy K M, et al. J. Hazard. Mater., 2009, 35:459-467
20. [20]
  Li J R, Du M, Bu X H, et al. J. Solid State Chem., 2003, 173:20-26 doi: 10.1016/S0022-4596(03)00055-0
21. [21]
  Murugesapandian B, Roseky P W. Eur. J. Inorg. Chem., 2011, 26:4103-4108
22. [22]
  Berg N, Taylor S M, Prescimone A, et al. CrystEngComm, 2012, 14:2732-2738 doi: 10.1039/c2ce25047k
23. [23]
  Sultan M, Tahir A A, Mazhar M, et al. New J. Chem., 2012, 36:911-917 doi: 10.1039/c2nj20789c
24. [24]
  An J, Shade C M, Chengelis-Czegan D A, et al. J. Am. Chem. Soc., 2011, 133:1220-1223 doi: 10.1021/ja109103t
25. [25]
  Gole B, Bar A K, Mukherjee P S. Chem. Commun., 2011, 47:12137-12139 doi: 10.1039/c1cc15594f
26. [26]
  Yang X G, Jia L R, Fang S M. Synth. React. Inorg. Met. Org. Nano-Met. Chem., 2013, 43:325-331 doi: 10.1080/15533174.2012.740730
27. [27]
  Wang Y L, Fu J H, Jiang Y L, et al. CrystEngComm, 2012, 14:7245-7252 doi: 10.1039/c2ce25938a
28. [28]
  Liu J M, Lin X, Wei C J, et al. Microchim. Acta, 2004, 148: 267-272 doi: 10.1007/s00604-004-0271-x
29. [29]
  ChangHN, Hou S X, Cui G H, et al. J. Inorg. Organomet. Polym. Mater., 2017, 27:518-527 doi: 10.1007/s10904-016-0494-4
30. [30]
  Qin L, Zheng X H, Xiao S L, et al. Trans. Met. Chem., 2013, 38:891-897 doi: 10.1007/s11243-013-9764-y
31. [31]
  Zhao X X, Hao Z C, Hou S X, et al. J. Inorg. Organomet. Polym. Mater., 2017, 27:934-940 doi: 10.1007/s10904-017-0538-4
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