Citation: JIANG Jian-Hui, LIANG Peng-Ju, LIU Su, ZHANG Jian-Bo, TU Kang-Nan. Efficient Synthesis Approach and Photocatalytic Property of Cu and Ni Doped ZnO[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 499-506. doi: 10.11862/CJIC.2018.072 shu

Efficient Synthesis Approach and Photocatalytic Property of Cu and Ni Doped ZnO

JIANG Jian-Hui ^1,2,3,, ,
LIANG Peng-Ju ^1,3 ,
LIU Su ^1,3 ,
ZHANG Jian-Bo ^1,3 ,
TU Kang-Nan ³

1.
Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, Alar, Xinjiang 843300, China
2.
State Key Laboratory of Organic-Inorganic Composites, Beijing 100029, China
3.
College of Life Sciences, Tarim University, Alar, Xinjiang 843300, China

Corresponding author: JIANG Jian-Hui, xjjjh78@163.com
Received Date: 14 October 2017
Revised Date: 21 December 2017

Figures(10)

An efficient route for the synthesis of Cu and Ni doped ZnO was developed in the presence of Zn(NO₃)₂, CuSO₄ and Ni(NO₃)₂ with Gemini surfactant as the soft template. Moreover, the photocatalyst was prepared by a hydrothermal method, and its structure was unambiguously configured by XRD, SEM-EDX, UV-Vis DRS and PL as well. In this paper, different influence parameters to synthesize the ZnO photocatalyst were investigated, such as reaction time, temperature, the doping amount of the Cu and Ni. By adopting the newly synthesized photocatalyst in the degradation of model pollutant RhB, the optimal conditions to afford the ZnO were finally developed. The results show that the degradation efficiency could reach 96.9% in the condition that hydrothermal process 130℃ for 8 h, calcination 500℃ for 3 h, and 10 mg·L^-1 RhB under the irradiation of 250 W high pressure mercury lamp with 0.8 g·L^-1 1.0%Cu-3.0%Ni/ZnO as photocatalyst.
- Cu, Ni doped,
- hydrothermal process,
- ZnO,
- photocatalysis,
- RhB
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