Citation: LI Jian, YU Min, LIU Guang-Xiang. Syntheses, Crystal Structures and Photoluminescent Properties of Two Cadmium(II) Coordination Polymers Constructed from Tris(4-imidazolylphenyl)amine[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 605-613. doi: 10.11862/CJIC.2018.069 shu

Syntheses, Crystal Structures and Photoluminescent Properties of Two Cadmium(II) Coordination Polymers Constructed from Tris(4-imidazolylphenyl)amine

Nanjing Key Laboratory of Advanced Functional Materials, School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: LIU Guang-Xiang, njuliugx@126.com
Received Date: 3 October 2017
Revised Date: 27 November 2017

Figures(9)

Two cadmium(Ⅱ) coordination polymers, [CdI(TIPA)(CDC)_0.5]_n (1) and {[Cd(TIPA)(MPDA)]·H₂O}_n (2), (TIPA=tris(4-imidazolylphenyl)amine, H₂CDC=1, 4-cyclohexanedicarboxylic acid, H₂MPDA=5-methylisophthalic acid), have been synthesized and characterized by IR spectroscopy, elemental analyses and single-crystal X-ray diffraction. Structural analyses reveal that complex 1 features a rare 2D→2D polyrotaxane network with (3, 4)-connected (4.5²)(4.5³.7²) topology, which is further interlinked into a higher-dimensional supramolecular framework by intermolecular weak interactions, whereas complex 2 has a two-dimensional (3, 5)-connected novel network with (4².6⁷.8)(4².6) topology and shows a 2D→3D parallel-parallel polycatenation framework. The results show that the carboxylates exert obvious influence on the resulting architectures. Meanwhile, the solid-state photoluminescence of two complexes at room temperature was also investigated.
- cadmium coordination polymer,
- tris (imidazole) ligands,
- polycarboxylate,
- crystal structure,
- photoluminescence
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