Citation: CAO Jiao-Lan, WANG Xi-Gui. Preparation and Luminescent Properties of Eu³⁺ Doped B₂O₃-CaO Luminescent Materials[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 325-330. doi: 10.11862/CJIC.2018.066 shu

Preparation and Luminescent Properties of Eu³⁺ Doped B₂O₃-CaO Luminescent Materials

CAO Jiao-Lan ,
WANG Xi-Gui ^,

College of Chemistry and Environment Science, Inner Mongolia Normal University, Hohhot 010022, China

Corresponding author: WANG Xi-Gui, wangxg@imnu.edu.cn
Received Date: 31 July 2017
Revised Date: 29 November 2017

Figures(6)

The high pure B₂O₃-CaO:Eu³⁺ phosphor is prepared by sol-gel method. The structures of samples obtained at different annealing temperatures are characterized by XRD and IR. It is found that the borate matrix with different structures can be formed with the change of annealing temperature. Based on the analysis of the excitation spectrum, emission spectrum and fluorescence decay curves of borate phosphors with different structures, the luminescent properties and luminescent mechanism of the phosphors are investigated. The result indicate that Eu³⁺ ions occupy no inversion symmetry site with the dominant electric dipole transition in borate matrix of the different structure, and these phosphors give off red light under ultraviolet excitation. The high pure CaB₂O₄ matrix obtained by annealing at 900℃ is most favorable for luminescence and the B₂O₃-CaO:Eu³⁺ phosphor have the longest fluorescence decay time. These are attributed to the fact that Eu³⁺ in the matrix is more likely to replace Ca²⁺ to form relatively large numbers of p-n junctions and traps.
- sol-gel,
- Eu³⁺ doped B₂O₃-CaO,
- luminescent properties,
- luminescent mechanism
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Preparation and Luminescent Properties of Eu³⁺ Doped B₂O₃-CaO Luminescent Materials