Citation: WANG Hong-Yan, ZHAO Yan-Peng, LÜ Wen-Miao, LU Ning-Yue, SHI Xiu-Feng, FAN Bin-Bin, LI Rui-Feng. Comparison on Catalytic Performance of 1, 10-Phenanthroline Cu(Ⅱ) Complexes Encapsulated in Zeolite-Y and Hierarchical Zeolite-Y[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 483-489. doi: 10.11862/CJIC.2018.061 shu

Comparison on Catalytic Performance of 1, 10-Phenanthroline Cu(Ⅱ) Complexes Encapsulated in Zeolite-Y and Hierarchical Zeolite-Y

College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: FAN Bin-Bin, fanbinbin@tyut.edu.cn
Received Date: 27 May 2017
Revised Date: 28 November 2017

Figures(7)

1, 10-phenanthroline Cu(Ⅱ) complexes (CuPhen) were successfully encapsulated in the cavities of conventional zeolite-Y and hierarchical zeolite-Y hosts obtained via post-treatment by the flexible ligand method. The physicochemical properties of the prepared hybrids were characterized by X-ray diffraction, TEM, Fourier transform infrared spectroscopy, Ultraviolet-visible spectroscopy and N₂ adsorption-desorption. A comparative study on the catalytic performances of the Cu complexes encapsulated in the different zeolite-Y hosts was carried out with different substrates. The results show that the hierarchical zeolite-Y exhibites superior host performance to the conventional zeolite-Y, and Cu complexes encapsulated in hierarchical zeolite-Y has higher catalytic activities in various cycloalkane oxidation reactions than those in the conventional zeolite-Y using H₂O₂ as the oxidant. In addition, Cu complexes encapsulated in the hierarchical zeolite-Y exhibites the same stability and reusability as those in the conventional zeolite-Y.
- hierarchical Y zeolites,
- metal complexes,
- encapsulation,
- catalytic oxidation
1. [1]
  Xuereb D J, Dzierzak J, Raja R. Catal. Today, 2012, 198(1): 19-34 doi: 10.1016/j.cattod.2012.04.050
2. [2]
  Fan B B, Li R F, Cao J H, et al. Chin. J. Catal., 2000, 21(1): 91-96
3. [3]
  Thibault-Starzyk F, Stan I, Abelló S, et al. J. Catal., 2009, 264(1):11-14 doi: 10.1016/j.jcat.2009.03.006
4. [4]
  Fan W, Snyder M A, Kumar S, et al. Nat. Mater., 2008, 7(12): 984-991 doi: 10.1038/nmat2302
5. [5]
  Na K, Jo C, Kim J, et al. Science, 2011, 333(6040):328-332 doi: 10.1126/science.1204452
6. [6]
  Groen J C, Jansen J C, Moulijn J A, et al. J. Phys. Chem. B, 2004, 108(35):13062-13065 doi: 10.1021/jp047194f
7. [7]
  Groen J C, Bach T, Ziese U, et al. J. Am. Chem. Soc., 2005, 127(31):10792-10793 doi: 10.1021/ja052592x
8. [8]
  Verboekend D, Nuttens N, Locus R, et al. Chem. Soc. Rev., 2016, 45(12):3331-3352 doi: 10.1039/C5CS00520E
9. [9]
  Verboekend D, Keller T C, Mitchell S, et al. Adv. Funct. Mater., 2013, 23(15):1923-1934 doi: 10.1002/adfm.v23.15
10. [10]
  Verboekend D, Vilé G, Pérez-Ramírez J. Adv. Funct. Mater., 2012, 22(5):916-928 doi: 10.1002/adfm.v22.5
11. [11]
  Mori K, Kagohara K, Yamashita H. J. Phys. Chem. C, 2008, 112(7):2593-2600 doi: 10.1021/jp709571v
12. [12]
  Jin C, Fan W B, Jia Y J, et al. J. Mol. Catal. A: Chem., 2006, 249(1):23-30
13. [13]
  Zhao J, Yin Y Y, Li Y, et al. Chem. Eng. J., 2016, 284:405-411 doi: 10.1016/j.cej.2015.08.143
14. [14]
  Korotchenko N M, Dobarkina V A, Skorik N A. Russ. J. Inorg. Chem., 2005, 50(11):1804-1809
15. [15]
  Bania K K, Deka R C. J. Phys. Chem. C, 2012, 116(27): 14295-14310 doi: 10.1021/jp3010376
16. [16]
  XIA Feng, LIU Zhao-Min, FAN Bin-Bin, et al. Chin. J. Catal., 2009, 30(7):601-605
17. [17]
  Godhani D R, Nakum H D, Parmar D K, et al. J. Mol. Catal. A: Chem., 2016, 415:37-55 doi: 10.1016/j.molcata.2016.01.024
18. [18]
  Osajima T, Deguchi T, Sanemasa I. Bull. Chem. Soc. Jpn., 1991, 64(6):2705-2709
1. [1]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
2. [2]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
3. [3]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
4. [4]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
5. [5]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
6. [6]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
7. [7]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
8. [8]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
9. [9]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
10. [10]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
11. [11]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
12. [12]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
15. [15]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
16. [16]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
17. [17]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
18. [18]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
19. [19]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
20. [20]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(2041)
HTML views(228)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142