Citation: LI Zhi-Jun, ZHANG Jing, WEI Xue-Hong, CAI Jin, WU Li-Xin. Chiral Supramolecular Liquid Crystal Based on Polyoxometalate[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 353-358. doi: 10.11862/CJIC.2018.050 shu

Chiral Supramolecular Liquid Crystal Based on Polyoxometalate

LI Zhi-Jun ^1,3 ,
ZHANG Jing ^1,2,, ,
WEI Xue-Hong ^3,, ,
CAI Jin ¹ ,
WU Li-Xin ²

1.
Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China
2.
State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, China
3.
College of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China

Corresponding author: ZHANG Jing, jingzhang@sxu.edu.cn WEI Xue-Hong, xhwei@sxu.edu.cn
Received Date: 23 August 2017
Revised Date: 27 November 2017

Figures(7)

Taken chiral induction as the breakthrough point, the cholesterol-containing ammonium surfactant is employed to encapsulate the lacunary Keggin-type polyoxometalate, which yielding a chiral mesogenic cations modified polyoxometalate-containing hybrid supramolecular complex. The complex has optical activities which are induced by the peripheral chiral surfactants through electrostatic interactions, as demonstrated by the circular dichroism spectrum. The thermotropic behaviors of the complex are characterized by differential scanning calorimetry, polarized optical microscopy, and temperature-dependent X-ray diffraction, which indicating that the complex has liquid crystalline properties with a typical SmA^* mesophase over a wide temperature range.
- polyoxometalate,
- liquid crystal,
- chiral supramolecule,
- self-assembly,
- surfactant
1. [1]
  Song Q, Li F, Wang Z Q, et al. Chem. Sci., 2015, 6(8):3342-3346
2. [2]
  Zhao Q, Wang Y, Yan Y, et al. ACS Nano, 2014, 8(11):11341-11349 doi: 10.1021/nn5042366
3. [3]
  QIU Sheng-Chao, LI Qing, ZHANG Yun-Qian, et al. Chinese. J. Inorg. Chem., 2016, 32(7):1303-1310 doi: 10.11862/CJIC.2016.154
4. [4]
  Tan X P, Li Z, Xia M, et al. RSC Adv., 2016, 6(24):20021-20026 doi: 10.1039/C6RA00065G
5. [5]
  Zheng Z G, Li Y N, Bisoyi H K, et al. Nature, 2016, 531(7594):352-356 doi: 10.1038/nature17141
6. [6]
  Tang J C, Huang R, Gao H F, et al. RSC Adv., 2012, 2(7):2842-2847 doi: 10.1039/c2ra01362b
7. [7]
  Yao B, Cong Y H, Zhang B Y, et al. RSC Adv., 2016, 6(48):42745-42750 doi: 10.1039/C6RA07388C
8. [8]
  Zou W J, Yan Y, Fang J, et al. J. Am. Chem. Soc., 2014, 136(2):578-581 doi: 10.1021/ja409796b
9. [9]
  Zhao Y Z, Zhang L Y, He Z M, et al. Liq. Cryst., 2015, 42(8):1120-1123 doi: 10.1080/02678292.2015.1025871
10. [10]
  Lin P C, Cong Y H, Sun, C, et al. Nanoscale, 2016, 8(4):2403-2411 doi: 10.1039/C5NR07620J
11. [11]
  Qi H, Kinkead B, Hegmann T. Adv. Funct. Mater., 2008, 18(2):212-221 doi: 10.1002/(ISSN)1616-3028
12. [12]
  Mori T, Sharma A, Hegmann T. ACS Nano, 2016, 10(1):1552-1564 doi: 10.1021/acsnano.5b07164
13. [13]
  Archbold C T, Davis E J, Mandle R J, et al. Soft Matter, 2015, 11(38):7547-7557 doi: 10.1039/C5SM01935D
14. [14]
  Watanabe K, Osaka I, Yorozuya S, et al. Chem. Mater., 2012, 24(6):1011-1024 doi: 10.1021/cm2028788
15. [15]
  Nguyen T D, Hamad W Y, MacLachlan M J. Adv. Funct. Mater., 2014, 24(6):777-783 doi: 10.1002/adfm.201302521
16. [16]
  WANG Bin, WANG Xiao-Hong, WU Ying-Ga, et al. Chinese. J. Inorg. Chem., 2016, 32(6):994-1000 doi: 10.11862/CJIC.2016.122
17. [17]
  Wang L H, Xu L, Mu Z C, et al. J. Mater. Chem., 2012, 22(44):23627-23632 doi: 10.1039/c2jm35314h
18. [18]
  Zhang J, Liu Y, Li Y, et al. Angew. Chem. Int. Ed., 2012, 51(19):4598-4602 doi: 10.1002/anie.201107481
19. [19]
  Yang H K, Ren L J, Wu H, et al. New J. Chem., 2016, 40(2):954-961 doi: 10.1039/C5NJ02271A
20. [20]
  Li W, Bu W F, Li H L, et al. Chem. Commun., 2005(30):3785-3787 doi: 10.1039/b503550c
21. [21]
  Wu H L, Zhang Z M, Li Y G, et al. RSC Adv., 2014, 4(82):43806-43810 doi: 10.1039/C4RA07525K
22. [22]
  He P L, Xu B, Xu X B, et al. Chem. Sci., 2016, 7(2):1011-1015 doi: 10.1039/C5SC03554F
23. [23]
  Li B, Zhang J, Wang S, et al. Eur. J. Inorg. Chem., 2013, 2013(10/11):1869-1875
24. [24]
  Polarz S, Smarsly B, Antonietti M. Chem. Phys. Chem., 2001, 2(7):457-461 doi: 10.1002/(ISSN)1439-7641
25. [25]
  Gao Y Q, Zhang Z M, Shen J Q, et al. CrystEngComm, 2014, 16(29):6784-6789 doi: 10.1039/c4ce00536h
26. [26]
  Nonaka K, Yamaguchi M, Yasui M. Chem. Commun., 2014, 50(70):10059-10061 doi: 10.1039/C4CC04227A
27. [27]
  Duan P F, Cao H, Zhang L, et al. Soft Matter, 2014, 10(30):5428-5448 doi: 10.1039/C4SM00507D
28. [28]
  Wang Y Z, Shi L, Yang Y, et al. Dalton Trans., 2014, 43(35):13178-13186 doi: 10.1039/C4DT00866A
29. [29]
  Zhang B, Guan W M, Zhang S M, et al. Chem. Commun., 2016, 52(30):5308-5311 doi: 10.1039/C5CC10033J
30. [30]
  Shi L, Jiang F R, Li B, et al. Dalton Trans., 2016, 45(22):16139-16143
31. [31]
  Wei X Y, Dickman M H, Pope M T. J. Am. Chem. Soc., 1998, 120(39):10254-10255 doi: 10.1021/ja980993p
32. [32]
  Majumdar K C, Shyam P K, Rao D S S, et al. J. Mater. Chem., 2011, 21(2):556-561 doi: 10.1039/C0JM02322A
33. [33]
  Zhang J, Li J F, Yuan H, et al. Chem. Asian J., 2016, 11(14):2001-2005 doi: 10.1002/asia.v11.14
34. [34]
  Haraguchi N, Okaue Y, Isobe T, et al. Inorg. Chem., 1994, 33(6):1015-1020 doi: 10.1021/ic00084a008
35. [35]
  Wang J, Yang G, Jiang H, et al. Soft Matter, 2013, 9(41):9785-9791 doi: 10.1039/c3sm51896e
36. [36]
  Yang J, Zhang Q H, Zhu L Y, et al. Chem. Mater., 2007, 19(10):2544-2550 doi: 10.1021/cm062675s
37. [37]
  Xiao S F, Lu X M, Lu Q H. Macromolecules, 2007, 40(22):7944-7950 doi: 10.1021/ma070972s
38. [38]
  Cheng X H, Bai X Q, Jing S, et al. Chem. Eur. J., 2010, 16(15):4588-4601 doi: 10.1002/chem.v16:15
39. [39]
  Xie H L, Jie C K, Yu Z Q, et al. J. Am. Chem. Soc., 2010, 132(23):8071-8080 doi: 10.1021/ja101184u
40. [40]
  Zhang L Y, Chen S, Zhao H, et al. Macromolecules, 2010, 43(14):6024-6032 doi: 10.1021/ma100847g
41. [41]
  Wang Q, Zhao B, Zhang X, et al. Langmuir, 2002, 18(25):9845-9852 doi: 10.1021/la020608g
42. [42]
  Li W, Yi S Y, Wu Y Q, et al. J. Phys. Chem. B, 2006, 110(34):16961-16966 doi: 10.1021/jp062074o
1. [1]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
2. [2]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
3. [3]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
4. [4]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
5. [5]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
6. [6]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
7. [7]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
8. [8]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
9. [9]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
10. [10]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
11. [11]
  Haiying Wang , Andrew C.-H. Sue . How to Visually Identify Homochiral Crystals. University Chemistry, 2024, 39(3): 78-85. doi: 10.3866/PKU.DXHX202309004
12. [12]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
13. [13]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
14. [14]
  Conghao Shi , Ranran Wang , Juli Jiang , Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034
15. [15]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . Kinetic Resolution Enabled by Photoexcited Chiral Copper Complex-Mediated Alkene E→Z Isomerization: A Comprehensive Chemistry Experiment for Undergraduate Students. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
16. [16]
  Jia Yao , Xiaogang Peng . Theory of Macroscopic Molecular Systems: Theoretical Framework of the Physical Chemistry Course in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 27-37. doi: 10.12461/PKU.DXHX202408117
17. [17]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
18. [18]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
19. [19]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
20. [20]
  Rui Li , Jiayu Zhang , Anyang Li . Two Levels of Understanding of Chemical Bonds: a Case of the Bonding Model of Hypervalent Molecules. University Chemistry, 2024, 39(2): 392-398. doi: 10.3866/PKU.DXHX202308051

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1607)
HTML views(223)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142