Citation: ZHU Hong-Yu, YANG Han-Pei, SUN Hui-Hua, GAO Zhao, MAO Jing-Tao, WU Jun-Ming. Highly Uniform Monolayer-Carbon Nanocages: Facile Synthesis, Simple Modification and Adsorptive Properties for Aqueous Crystal Violet[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 445-453. doi: 10.11862/CJIC.2018.047 shu

Highly Uniform Monolayer-Carbon Nanocages: Facile Synthesis, Simple Modification and Adsorptive Properties for Aqueous Crystal Violet

Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098, China

Corresponding author: YANG Han-Pei, yanghanpei@hhu.edu.cn
Received Date: 23 August 2017
Revised Date: 12 December 2017

Figures(12)

Three-dimensional structures of monolayer and hollow carbon nanocages were obtained by a facile method. These nanocages with controlled wall thickness are synthesized by catalytic templating on magnesium oxides (MgO), nucleating in situ during annealing of basic magnesium carbonate, using absolute ethyl alcohol as an inexpensive precursor of carbon, and following the MgO dissolution by dilute nitric acid solution. The obtained CNCs show a specific surface area as high as 906 m²·g^-1, and conduct an adsorption capacity of 542.6 mg·g^-1 for aqueous crystal violet under experimental conditions. The hydrophilia of as-prepared CNCs can be significantly improved through a simple modification by treating CNCs with sodium dodecyl benzene sulfonate, and the hydrophilic CNCs can capture CV molecules with an adsorption capacity saturated in 748.4 mg·g^-1. The pristine and modified CNCs were extensively characterized by XRD, FT-IR, TEM, XPS and BET surface measurement, and the structure-performance of CNCs is careful correlated. The chemical adsorption mechanism during the removal of CV by CNCs is identified, and the interactions between CV and CNCs, through π-π and electrovalent bonds are proposed.
- carbon nanocages,
- surface modification,
- sodium dodecyl benzene sulfonate,
- crystal violet,
- adsorption
1. [1]
  Bhatt A S, Sakaria P L, Vasudevan M, et al. RSC Adv., 2012, 2(23):8663-8671 doi: 10.1039/c2ra20347b
2. [2]
  Chen H, Zhao J. Adsorption, 2009, 15(4):381-389 doi: 10.1007/s10450-009-9155-z
3. [3]
  Ngulube T, Gumbo J R, Masindi V, et al. J. Environ. Manage., 2017, 191:35-57 doi: 10.1016/j.jenvman.2016.12.031
4. [4]
  Yagub M T, Sen T K, Afroze S, et al. Adv. Colloid Interface Sci., 2014, 209:172-184 doi: 10.1016/j.cis.2014.04.002
5. [5]
  Crini G. Bioresour. Technol., 2006, 97(9):1061-1085 doi: 10.1016/j.biortech.2005.05.001
6. [6]
  Giannakoudakis D A, Kyzas G Z, Avranas A, et al. J. Mol. Liq., 2016, 213:381-389 doi: 10.1016/j.molliq.2015.07.010
7. [7]
  Gupta V K, Suhas. J. Environ. Manage., 2009, 90(8):2313-2342
8. [8]
  Wu Q, Yang L J, Wang X Z, et al. Acc. Chem. Res., 2017, 50(2):435-444 doi: 10.1021/acs.accounts.6b00541
9. [9]
  Ziolkowska D A, Jangam J S D, Rudakov G, et al. Carbon, 2017, 115:617-624 doi: 10.1016/j.carbon.2017.01.055
10. [10]
  Pupysheva O V, Farajian A A, Yakobson B I. Nano Lett., 2008, 8(3):767-774 doi: 10.1021/nl071436g
11. [11]
  Vinu A, Miyahara M, Sivamurugan V, et al. J. Mater. Chem., 2005, 15(48):5122-5127 doi: 10.1039/b507456h
12. [12]
  Schaper A K, Hou H, Greiner A, et al. Appl. Phys. A: Mater. Sci. Process., 2004, 78(1):73-77 doi: 10.1007/s00339-003-2199-0
13. [13]
  Tadokoro M, Tsumeda S, Tsuhara N, et al. J. Nanosci. Nanotechnol., 2009, 9(1):391-395 doi: 10.1166/jnn.2009.J042
14. [14]
  Lim K H, Oh H S, Kim H. Electrochem. Commun., 2009, 11(6):1131-1134 doi: 10.1016/j.elecom.2009.03.030
15. [15]
  Oh H S, Lim K H, Roh B, et al. Electrochim. Acta, 2009, 54(26):6515-6521 doi: 10.1016/j.electacta.2009.06.028
16. [16]
  Li G D, Yu H X, Xu L Q, et al. Nanoscale, 2011, 3(8):3251-3257 doi: 10.1039/c1nr10284b
17. [17]
  Burke D M, O'Byrne J P, Fleming P G, et al. Desalination, 2011, 280(1):87-94
18. [18]
  Petala E, Georgiou Y, Kostas V, et al. ACS Sustainable Chem. Eng., 2017, 5(7):5782-5792 doi: 10.1021/acssuschemeng.7b00394
19. [19]
  Sun L, Wan S G, Luo W S. Bioresour. Technol., 2013, 140: 406-413 doi: 10.1016/j.biortech.2013.04.116
20. [20]
  Din A T M, Hameed B H, Ahmad A L. J. Hazard. Mater., 2009, 161(2):1522-1529
21. [21]
  Tan I A W, Ahmad A L, Hameed B H. J. Hazard. Mater., 2009, 164(2):473-482
22. [22]
  Li G D, Xu L Q, Hao Q, et al. RSC Adv., 2012, 2(1):284-291 doi: 10.1039/C1RA00631B
23. [23]
  Li H B, Yue Q L, Xu S L, et al. Mater. Lett., 2012, 66(1): 353-356 doi: 10.1016/j.matlet.2011.08.103
24. [24]
  Qin H F, Huang Y K, Liu S Y, et al. J. Nanomater., 2015, 2015:604201(8 Pages)
25. [25]
  Zhang H, Li X, Zhang D, et al. Carbon, 2016, 103:480-487 doi: 10.1016/j.carbon.2016.03.042
26. [26]
  Zhang J, Yang C P, Yin Y X, et al. Adv. Mater., 2016, 28(43):9539-9544 doi: 10.1002/adma.201602913
27. [27]
  Zhao X G, Huang L Q. Ceram. Int., 2017, 43(5):3975-3980 doi: 10.1016/j.ceramint.2016.11.083
28. [28]
  Estrade-Szwarckopf H. Carbon, 2004, 42(8):1713-1721
29. [29]
  XIN Qin, LUO Meng-Fei. Modern Catalytic Research Methods. Beijing: Science Press, 2009.
30. [30]
  Gupta V K, Gupta B, Rastogi A, et al. J. Hazard. Mater., 2011, 186(1):891-901 doi: 10.1016/j.jhazmat.2010.11.091
31. [31]
  Hong C Y, Sheng Z M, Hu M H, et al. RSC Adv., 2016, 6(65):59896-59899 doi: 10.1039/C6RA10803B
32. [32]
  Huang Y H, Chen J H, Sun X, et al. Sens. Actuators, B, 2015, 212:165-173 doi: 10.1016/j.snb.2015.02.013
33. [33]
  XIA Jing-Zhu, WANG Li-Wei, HU Ren-Zhi, et al. Chinese J. Inorg. Chem., 2014, 30(9):2099-2104
34. [34]
  Tan X L, Fang M, Chen C L, et al. Carbon, 2008, 46(13): 1741-1750 doi: 10.1016/j.carbon.2008.07.023
35. [35]
  Bouraada M, Lafjah M, Ouali M S, et al. J. Hazard. Mater., 2008, 153(3):911-918 doi: 10.1016/j.jhazmat.2007.09.076
36. [36]
  Wang B, Zhang H, Evans D G, et al. Mater. Chem. Phys., 2005, 92(1):190-196 doi: 10.1016/j.matchemphys.2005.01.013
37. [37]
  Shen X B, Dai J Y, Liu Y, et al. Polymer, 2017, 122:258-269 doi: 10.1016/j.polymer.2017.06.075
38. [38]
  Lin P, Li B L, Li J T, et al. Catal. Lett., 2011, 141(3):459-466 doi: 10.1007/s10562-010-0526-6
39. [39]
  Wei X H, Wu Z L, Du C F, et al. J. Taiwan Inst. Chem. Eng., 2017, 77:257-262 doi: 10.1016/j.jtice.2017.04.004
40. [40]
  Islam M F, Rojas E, Bergey D M, et al. Nano Lett., 2003, 3(2):269-273 doi: 10.1021/nl025924u
41. [41]
  Tasis D, Tagmatarchis N, Georgakilas V, et al. Chem. Eur. J., 2003, 9(17):4000-4008 doi: 10.1002/(ISSN)1521-3765
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