Citation: WANG Dan, LIU Li-Lai, LI Ming-Xian, PAN Xiao-Na, ZHAO Yan-Hong, ZHANG Jin-Qiu, AN Mao-Zhong, YANG Pei-Xia. Preparation of Platinum Nanoparticles via Electrochemical Method in N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate Ionic Liquid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 409-414. doi: 10.11862/CJIC.2018.045 shu

Preparation of Platinum Nanoparticles via Electrochemical Method in N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate Ionic Liquid

1.
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
2.
College of Environmental and Chemical Engineering, Heilongjiang University of Science and Technology, Harbin 150022, China
3.
Shenzhen BAK Power Battery Co., Ltd., Shenzhen, Guangdong 518119, China

Corresponding author: YANG Pei-Xia, yangpeixia@hit.edu.cn
Received Date: 12 September 2017
Revised Date: 5 November 2017

Figures(7)

Platinum nanoparticles were prepared via a potentiostatic electrodeposition method on a glassy carbon electrode from N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([DEME] [BF₄]) ionic liquid. At first, the effects of different deposition potentials and deposition times on the micromorphology of platinum nanoparticles were investigated. It has been found that the mean size of Pt nanoparticles obtained at -2.5 V for 480 s was estimated to be ca. 2.38 nm from the SEM and TEM images. Its face-centered cubic (fcc) crystal structure was confirmed by high-resolution transmission electron microscopy (HRTEM) and electron diffraction (SAED). At the same time, Platinum nanoparticles exposed significant (110) and (100) planes in sulfuric acid. Further study of the deposition behavior of platinum reveals that the diffusion process and the electrochemical process controll the two-step reduction of Pt(Ⅳ) together.
- ionic liquid,
- Pt,
- electrodeposition,
- fuel cell
1. [1]
  Antoniassi R M, Otubo L, Vaz J M, et al. J. Catal., 2016, 342:67-74 doi: 10.1016/j.jcat.2016.07.022
2. [2]
  Pullamsetty A, Sundara R. J. Colloid Interface Sci., 2016, 479:260-270 doi: 10.1016/j.jcis.2016.06.069
3. [3]
  Zhang J, Yi X B, Liu S, et al. J. Phys. Chem. Solids, 2017, 102:99-104 doi: 10.1016/j.jpcs.2016.11.006
4. [4]
  Pajić M N K, Stevanović S I, Radmilović V V, et al. J. Solid State Electrochem., 2016, 20(12):3405-3414 doi: 10.1007/s10008-016-3319-z
5. [5]
  Chu Y Y, Wang Z B, Gu D M, et al. J. Power Sources, 2010, 195:1799-1804 doi: 10.1016/j.jpowsour.2009.10.039
6. [6]
  Bharti A, Cheruvally G, Muliankeezhu S. Int. J. Hydrogen Energy, 2017, 42(16):11622-11631 doi: 10.1016/j.ijhydene.2017.02.109
7. [7]
  Liu S, Wang J Q, Zeng J, et al. J. Power Sources, 2010, 195(15):4628-4633 doi: 10.1016/j.jpowsour.2010.02.024
8. [8]
  Hsieh C T, Wei J M, Lin J S, et al. Catal. Commun., 2011, 16(1):220-224 doi: 10.1016/j.catcom.2011.09.030
9. [9]
  Ye F, Wang T T, Li J J, et al. J. Electrochem. Soc., 2009, 156(8):B981-B985 doi: 10.1149/1.3151868
10. [10]
  Ruengkit C, Tantavichet N. Thin Solid Films, 2017, 636(31):116-126
11. [11]
  Zhang Y Y, Li F P, Liu X Q, et al. Electrochim. Acta, 2017, 242:165-172 doi: 10.1016/j.electacta.2017.05.020
12. [12]
  Hussain S, Erikson H, Kongi N, et al. Int. J. Hydrogen Energy, 2017, 42(9):5958-5970 doi: 10.1016/j.ijhydene.2016.11.164
13. [13]
  Alexeeva O K, Fateev V N. Int. J. Hydrogen Energy, 2016, 41(5):3373-3386 doi: 10.1016/j.ijhydene.2015.12.147
14. [14]
  Fouda-Onana F, Guillet N, AlMayouf A M. J. Power Sources, 2014, 271:401-405 doi: 10.1016/j.jpowsour.2014.08.031
15. [15]
  Endres F, Bukowski M, Hempelmann R, et al. Angew. Chem. Int. Ed., 2003, 42(29):3428-3430 doi: 10.1002/anie.200350912
16. [16]
  Abbott A P, McKenzie K J. Phys. Chem. Chem. Phys., 2006, 8(37):4265-4279 doi: 10.1039/b607329h
17. [17]
  He P, Liu H T, Li Z Y, et al. J. Electrochem. Soc., 2005, 152(4):E146-E153 doi: 10.1149/1.1870754
18. [18]
  Yu P, Qian Q, Wang X, et al. J. Mater. Chem., 2010, 20(28):5820-5822 doi: 10.1039/c0jm01293a
19. [19]
  Zhang D, Chang W C, Okajima T, et al. Langmuir, 2011, 27(23):14662-14668 doi: 10.1021/la202992m
20. [20]
  Giordano N, Passalacqua E, Pino L, et al. Electrochim. Acta, 1991, 36(13):1979-1984 doi: 10.1016/0013-4686(91)85082-I
21. [21]
  Solla-Gullón J, Vidal-Iglesias F J, Rodriguez P, et al. J. Phys. Chem. B, 2004, 108(36):13573-13575 doi: 10.1021/jp0471453
22. [22]
  Markovic N, Gasteiger H, Ross P N. J. Electrochem. Soc., 1997, 144(5):1591-1597 doi: 10.1149/1.1837646
23. [23]
  Wang C, Daimon H, Onodera T, et al. Angew. Chem. Int. Ed., 2008, 47(19):3588-3591 doi: 10.1002/(ISSN)1521-3773
24. [24]
  Markovic N M, Gasteiger H A, Ross Jr P N. J. Phys. Chem., 1995, 99(11):3411-3415 doi: 10.1021/j100011a001
25. [25]
  Xiaowei Y, Maozhong A, Yunwang Z, et al. Electrochim. Acta, 2011, 58:516-522 doi: 10.1016/j.electacta.2011.09.078
26. [26]
  YANG Xiao-Wei, ZHANG Yun-Wang, AN Mao-Zhong, et al. Chinese J. Inorg. Chem., 2012, 28(12):2617-2625
27. [27]
  Jayakumar M, Venkatesan K A, Srinivasan T G. Electrochim. Acta, 2007, 52(24):7121-7127 doi: 10.1016/j.electacta.2007.05.049
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1.
沈阳化工大学材料科学与工程学院沈阳 110142