Citation: FENG Qiu-Ju, SHI Xiao-Chi, XING Yan, LI Fang, LI Tong-Tong, PAN De-Zhu, LIANG Hong-Wei. Fabrication and Characteristics of Thermoelectric Microgenerators Based on Single Sb Doped ZnO Microwire[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 331-336. doi: 10.11862/CJIC.2018.042 shu

Fabrication and Characteristics of Thermoelectric Microgenerators Based on Single Sb Doped ZnO Microwire

1.
School of Physics and Electronic Technology, Liaoning Normal University, Dalian, Liaoning 116029, China
2.
School of Microelectronics, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: FENG Qiu-Ju, qjfeng@dlut.edu.cn
Received Date: 16 August 2017
Revised Date: 17 October 2017

Figures(9)

Large-scale Sb doped ZnO microwire arrays were grown by chemical vapor deposition method without using metal catalyst. The experimental results show that the length of the microwires is about 1~2.5 cm and the Sb concentration in microwires is about 3.1%(n/n). Moreover, thermoelectric generators were fabricated based on single Sb doped large-scale ZnO microwires. The influence of the length and diameter of microwires on the output characteristics of devices was investigated. Under a temperature difference of 20 K between two electrodes and the length of 1.6 cm, the devices can produce a maximum output voltage of about 36 mV, a maximum output power of about 10.8 nW. The single Sb-doped ZnO microwires show a Seebeck coefficient of about -1.80 mV·K^-1. In addition, it is found that the output voltages of the thermoelectric device increase with the microwire length, and decrease with the microwire diameters.
- chemical vapor deposition,
- Sb doped,
- ZnO microwires,
- thermoelectric generators
1. [1]
  An Q S, Zhang F J, Zhang J, et al. Energy Environ. Sci., 2016, 9:281-322 doi: 10.1039/C5EE02641E
2. [2]
  Hiralal P, Unalan H E, Amaratunga G A. Nanotechnol., 2012, 23:194002 doi: 10.1088/0957-4484/23/19/194002
3. [3]
  Wang X L, Shi G Q. Energy Environ. Sci., 2015, 8:790-823 doi: 10.1039/C4EE03685A
4. [4]
  Mai L Q, Tian X C, Xu X, et al. Chem. Rev., 2014, 114:11828-11862 doi: 10.1021/cr500177a
5. [5]
  Xue F, Zhang L M, Feng X L, et al. Nano Res., 2015, 8(7):2390-2399 doi: 10.1007/s12274-015-0749-3
6. [6]
  Mai L Q, Zhang Q J, Nan C W. Adv. Mater., 2017, 29:1701082 doi: 10.1002/adma.v29.20
7. [7]
  Wang Z L, Song J H. Science, 2006, 312:242-245 doi: 10.1126/science.1124005
8. [8]
  WANG Yuan-You, GONG Ai-Qing, YU Wen-Hua. Chinese J. Inorg. Chem., 2017, 33(3):509-518 doi: 10.11862/CJIC.2017.061
9. [9]
  Zhao B, Wang F, Chen H Y, et al. Nano Lett., 2015, 15:3988-3993 doi: 10.1021/acs.nanolett.5b00906
10. [10]
  Shi L L, Wang F, Li B H, et al. J. Mater. Chem. C, 2014, 2:5005-5010 doi: 10.1039/c3tc32547d
11. [11]
  ZHAO Xiao-Hua, SU Shuai, WU Guang-Li, et al. Chinese J. Inorg. Chem., 2017, 33(2):276-284 doi: 10.11862/CJIC.2017.021
12. [12]
  Yang Y, Qi J J, Guo W, et al. CrystEngComm, 2010, 12:2005-2007 doi: 10.1039/b927165a
13. [13]
  Yang Y, Qi J J, Zhang Y, et al. Appl. Phys. Lett., 2010, 97:223113 doi: 10.1063/1.3524231
14. [14]
  Sebald G, Guyomar D, Agbossou A. Smart Mater. Struct., 2009, 18:125006 doi: 10.1088/0964-1726/18/12/125006
15. [15]
  Feng Q J, Liu J Y, Lu J Y, et al. Mater. Sci. Semicond. Process., 2015, 40:436-438 doi: 10.1016/j.mssp.2015.07.010
16. [16]
  Feng Q J, Liang H W, Mei Y Y, et al. J. Mater. Chem. C, 2015, 3:4678-4682 doi: 10.1039/C4TC02878C
17. [17]
  Meyer B K, Alves H, Hofmann D M, et al. Phys. Status Solidi B, 2004, 241(2):231-260 doi: 10.1002/(ISSN)1521-3951
18. [18]
  Xiu F X, Yang Z, Mandalapu L J, et al. Appl. Phys. Lett., 2005, 87:152101 doi: 10.1063/1.2089183
19. [19]
  Li Z, Sun Q, Yao X D, et al. J. Mater. Chem., 2012, 22:22821-22831 doi: 10.1039/c2jm33899h
20. [20]
  Choi J Y, Cho K, Kim S. Nanotechnology, 2013, 24:455402 doi: 10.1088/0957-4484/24/45/455402
21. [21]
  Chen T G, Yu P, Chou R H, et al. Opt. Express, 2010, 18:467-476 doi: 10.1364/OE.18.00A467
22. [22]
  Yang Y, Pradel K C, Jing Q S, et al. ACS Nano, 2012, 6:6984-6989 doi: 10.1021/nn302481p
23. [23]
  Xu E Z, Li Z, Martinez J A, et al. Nanoscale, 2015, 7:2869-2876 doi: 10.1039/C4NR05870D
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沈阳化工大学材料科学与工程学院沈阳 110142