Citation: ZHANG Shu-Quan, ZHANG Jian-Han, GU Jia-Fang. Four Cadmium-Organic Coordination Polymers: Influence of Secondary Ligands to Crystal Structure and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 237-246. doi: 10.11862/CJIC.2018.039 shu

Four Cadmium-Organic Coordination Polymers: Influence of Secondary Ligands to Crystal Structure and Luminescent Properties

1.
Zhicheng College, Fuzhou University, Fuzhou 350002, China
2.
School of Resources and Chemical Engineering, Sanming University, Sanming, Fujian 365004, China

Corresponding author: ZHANG Shu-Quan, sqzhang@fzu.edu.cn
Received Date: 7 August 2017
Revised Date: 30 November 2017

Figures(6)

Four cadmium-organic coordination polymers, namely[Cd(Hncpoi)(2, 2'-bpy)(H₂O)]_n (1), {[Cd₂(Hncpoi)₂(bpyp)(H₂O)₄]·3H₂O}_n (2), {[Cd₂(Hncpoi)₂(azpy)(H₂O)₂]·2H₂O}_n (3), {[Cd₂(Hncpoi)₂(dpe)(H₂O)₂]·2H₂O}_n (4), have been solvothermally constructed from multi-carboxylic organic ligand 5-(2-Nitro-4-carboxyphenoxy)-isophthalic acid(H₃ncpoi), Cd²⁺ ions, and different auxiliary ligands:2, 2'-bipyridyl(2, 2'-bpy), 1, 4-bis-(4-pyridylmethyl)piperazine(bpyp), 4, 4'-azopyridine (azpy) and 1, 2-di(4-pyridyl)ethylene(dpe), respectively. These complexes were further characterized by single-crystal X-ray diffraction, PXRD, elemental analysis, and TG. Single-crystal X-ray diffraction showed that complexes 1 and 2 exhibit 1D chain-like structure, and complexes 3 and 4 are 2D (4, 4) grid layered structure. 1D chains or 2D layers of these complexes further assemble to 3D supramolecular architectures via intermolecular interactions. The coordination modes and configurations of secondary ligands have a crucial influence to the crystal structures of these complexes. Meanwhile, the photoluminescent properties of these complexes were also studied. The results showed that there are close relationship between the secondary ligands and photoluminescence properties of these coordination polymers.
- coordination polymer,
- crystal structure,
- photoluminescence spectrum,
- secondary ligand
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沈阳化工大学材料科学与工程学院沈阳 110142